6-Methoxycarbonyl-3-cyclohexene-1-carboxylicacid
Names
[ CAS No. ]:
88335-93-7
[ Name ]:
6-Methoxycarbonyl-3-cyclohexene-1-carboxylicacid
[Synonym ]:
6-(methoxycarbonyl)cyclohex-3-ene-1-carboxylic acid
6-Methoxycarbonyl-3-cyclohexene-1-carboxylic acid
MFCD00075490
4-Cyclohexene-1,2-dicarboxylic acid, monomethyl ester
6-(Methoxycarbonyl)-3-cyclohexene-1-carboxylic acid
6-Methoxycarbonyl-3-cyclohexene-1-carboxylicacid
Chemical & Physical Properties
[ Density]:
1.2±0.1 g/cm3
[ Boiling Point ]:
306.5±42.0 °C at 760 mmHg
[ Melting Point ]:
65-67ºC
[ Molecular Formula ]:
C9H12O4
[ Molecular Weight ]:
184.189
[ Flash Point ]:
121.3±21.4 °C
[ Exact Mass ]:
184.073563
[ PSA ]:
63.60000
[ LogP ]:
0.92
[ Vapour Pressure ]:
0.0±1.4 mmHg at 25°C
[ Index of Refraction ]:
1.504
Safety Information
[ Personal Protective Equipment ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter
[ Hazard Codes ]:
Xn
[ RIDADR ]:
NONH for all modes of transport
Articles
Chem. Pharm. Bull. 38(2) , 350-4, (1990)
A versatile chiral synthon, (1R,6S)-6-methoxycarbonyl-3-cyclohexene-1-carboxylic acid, was obtained by an enantioselective hydrolysis of the corresponding meso diester with pig liver esterase. This en...
N. Tamura et al.Tetrahedron Lett. 27 , 3749, (1986)
W. Boland et al.
Helv. Chim. Acta 68 , 2062, (1985)