N,O-Di-Boc-hydroxylamine
Names
[ CAS No. ]:
85006-25-3
[ Name ]:
N,O-Di-Boc-hydroxylamine
[Synonym ]:
Carbamic acid, N-[[(1,1-dimethylethoxy)carbonyl]oxy]-, 1,1-dimethylethyl ester
tert-butyl N-[(tert-butoxycarbonyl)oxy]carbamate
tert-butyl [(2-methylpropan-2-yl)oxycarbonylamino] carbonate
EINECS 285-055-0
2-Methyl-2-propanyl ({[(2-methyl-2-propanyl)oxy]carbonyl}oxy)carbamate
MFCD00034797
Chemical & Physical Properties
[ Density]:
1.1±0.1 g/cm3
[ Melting Point ]:
67-70ºC(lit.)
[ Molecular Formula ]:
C10H19NO5
[ Molecular Weight ]:
233.262
[ Exact Mass ]:
233.126328
[ PSA ]:
73.86000
[ LogP ]:
2.70
[ Index of Refraction ]:
1.443
MSDS
Safety Information
[ Symbol ]:
GHS07
[ Signal Word ]:
Warning
[ Hazard Statements ]:
H315-H319-H335
[ Precautionary Statements ]:
P261-P305 + P351 + P338
[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves
[ Hazard Codes ]:
Xi: Irritant;
[ Risk Phrases ]:
R36/37/38
[ Safety Phrases ]:
26-36
[ RIDADR ]:
NONH for all modes of transport
[ WGK Germany ]:
3.0
[ HS Code ]:
2924199090
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Customs
[ HS Code ]: 2924199090
[ Summary ]:
2924199090. other acyclic amides (including acyclic carbamates) and their derivatives; salts thereof. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%
Articles
Tetrahedron Lett. 35(23) , 6021-24, (1994)
A facile synthesis of N, O-bis (tert-butoxycarbonyl)-hydroxylamine. Staszak MA and Doecke CW.
Tetrahedron Lett. 34(44) , 7043-7044, (1993)
A convenient method for the preparation of hydroxamic acids. Reddy AS, et al.
Tetrahedron Lett. 41(33) , 6285-88, (2000)