purpurin
Names
[ CAS No. ]:
81-54-9
[ Name ]:
purpurin
[Synonym ]:
EINECS 201-359-8
Verantin
Purpurin
1,2,4-Trihydroxy-9,10-anthracenedione
C.I. Natural Red 16
natural red 16
1,2,4-Trihydroxy-9,10-anthraquinone
9,10-Anthracenedione, 1,2,4-trihydroxy-
Purpurine
C.I. Natural Red 8
1,2,4-trihydroxyanthracene-9,10-dione
1,2,4-trishydroxy-9,10-anthraquinone
1,2,4-Trihydroxyanthraquinone
Smoke Brown G
MFCD00001203
Hydroxylizaric acid
Biological Activity
[Description]:
[Related Catalog]:
[In Vivo]
[References]
Chemical & Physical Properties
[ Density]:
1.7±0.1 g/cm3
[ Boiling Point ]:
525.1±45.0 °C at 760 mmHg
[ Melting Point ]:
253-256ºC(lit.)
[ Molecular Formula ]:
C14H8O5
[ Molecular Weight ]:
256.210
[ Flash Point ]:
285.4±25.2 °C
[ Exact Mass ]:
256.037170
[ PSA ]:
94.83000
[ LogP ]:
4.60
[ Appearance of Characters ]:
Powder
[ Vapour Pressure ]:
0.0±1.4 mmHg at 25°C
[ Index of Refraction ]:
1.773
[ Storage condition ]:
2-8C
MSDS
Toxicological Information
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- CB8200000
- CHEMICAL NAME :
- Anthraquinone, 1,2,4-trihydroxy-
- CAS REGISTRY NUMBER :
- 81-54-9
- BEILSTEIN REFERENCE NO. :
- 1887127
- LAST UPDATED :
- 199612
- DATA ITEMS CITED :
- 6
- MOLECULAR FORMULA :
- C14-H8-O5
- MOLECULAR WEIGHT :
- 256.22
- WISWESSER LINE NOTATION :
- L C666 BV IVJ DQ EQ GQ
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
- TYPE OF TEST :
- Standard Draize test
- ROUTE OF EXPOSURE :
- Administration into the eye
- SPECIES OBSERVED :
- Rodent - rabbit
- TYPE OF TEST :
- LD - Lethal dose
- ROUTE OF EXPOSURE :
- Intraperitoneal
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- >500 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
MUTATION DATA
- TYPE OF TEST :
- Mutation in mammalian somatic cells
- TEST SYSTEM :
- Rodent - hamster Lung
- DOSE/DURATION :
- 20 mg/L
- REFERENCE :
- MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 240,1,1990
Safety Information
[ Symbol ]:
GHS07
[ Signal Word ]:
Warning
[ Hazard Statements ]:
H315-H319-H335
[ Precautionary Statements ]:
P261-P305 + P351 + P338
[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves
[ Hazard Codes ]:
Xi: Irritant;
[ Risk Phrases ]:
R36/37/38
[ Safety Phrases ]:
S26;S36
[ RIDADR ]:
NONH for all modes of transport
[ WGK Germany ]:
3
[ RTECS ]:
CB8200000
[ HS Code ]:
2914690090
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Customs
[ HS Code ]: 2914690090
[ Summary ]:
2914690090 other quinones。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:5.5%。General tariff:30.0%
Articles
Spectrochim. Acta. A. Mol. Biomol. Spectrosc. 149 , 997-1008, (2015)
In this work, we reported a combined experimental and theoretical study on molecular structure, vibrational spectra and Homo-Lumo analysis of Purpurin and TiO2/Purpurin. The geometries, electronic str...
Protection against the bacterial mutagenicity of heterocyclic amines by purpurin, a natural anthraquinone pigment.Mutat. Res. 444(2) , 451-61, (1999)
Purpurin (1,2,4-trihydroxy-9,10-anthraquinone) is a naturally occurring anthraquinone pigment found in species of madder root. We have found that the presence of purpurin in bacterial mutagenicity ass...
Toxicity and tumorigenicity of purpurin, a natural hydroxanthraquinone in rats: induction of bladder neoplasms.Cancer Lett. 102(1-2) , 193-8, (1996)
Chronic toxicity and tumorigenicity of purpurin, a natural hydroxyanthraquinone, was examined in two groups of male F344 rats. One group was given a basal diet mixed with purpurin at a concentration o...