Vanadium(V) trichloride oxide
Names
[ CAS No. ]:
7727-18-6
[ Name ]:
Vanadium(V) trichloride oxide
[Synonym ]:
MFCD00011459
oxovanadium,trihydrochloride
EINECS 231-780-2
Chemical & Physical Properties
[ Density]:
1.84 g/mL at 25 °C(lit.)
[ Boiling Point ]:
126-127 °C(lit.)
[ Melting Point ]:
−77 °C(lit.)
[ Molecular Formula ]:
Cl3OV
[ Molecular Weight ]:
173.30000
[ Flash Point ]:
126-127°C
[ Exact Mass ]:
171.84500
[ PSA ]:
17.07000
[ LogP ]:
1.94970
[ Vapour Pressure ]:
13.8 mm Hg ( 20 °C)
[ Index of Refraction ]:
1.6300
MSDS
Toxicological Information
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- YW2975000
- CHEMICAL NAME :
- Vanadium, trichlorooxo-
- CAS REGISTRY NUMBER :
- 7727-18-6
- LAST UPDATED :
- 199706
- DATA ITEMS CITED :
- 20
- MOLECULAR FORMULA :
- Cl3-O-V
- MOLECULAR WEIGHT :
- 173.29
- WISWESSER LINE NOTATION :
- VA G3-O
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 140 mg/kg
- REFERENCE :
- AIHAAP American Industrial Hygiene Association Journal. (AIHA, 475 Wolf Ledges Pkwy., Akron, OH 44311) V.19- 1958- Volume(issue)/page/year: 30,470,1969 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-AUSTRALIA:TWA 0.05 mg(V2O5)/m3 JAN 1993 OEL-BELGIUM:TWA 0.05 mg(V2O5)/m3 JAN 1993 OEL-DENMARK:TWA 0.03 mg(V2O5)/m3 JAN 1993 OEL-FINLAND:TWA 0.5 mg(V2O5)/m3 JAN 1993 OEL-FRANCE:TWA 0.05 mg(V2O5)/m3 JAN 1993 OEL-GERMANY:TWA 0.05 mg(V2O5)/m3 JAN 1993 OEL-HUNGARY:TWA 0.05 mg(V2O5)/m3;STEL 0.1 mg(V205)/m3 JAN 1993 OEL-JAPAN:TWA 0.5 mg(V2O5)/m3 JAN 1993 OEL-THE NETHERLANDS:TWA 0.5 mg(V2O5)/m3 JAN 1993 OEL-THE PHILIPPINES:TWA 0.25 mg(V205)/m3 JAN 1993 OEL-POLAND:TWA 0.5 mg(V2O5)/m3 JAN 1993 OEL-SWEDEN:STEL 0.05 mg(V2O5)/m3 JAN 1993 OEL-SWEDEN:TWA 0.2 mg(V2O5)/m3 (dust) JAN 1993 OEL-SWITZERLAND:TWA 0.05 mg(V2O5)/m3;STEL 0.25 mg(V2O5)/m3 JAN 1993 OEL-TURKEY:TWA 0.5 mg(V2O5)/m3 JAN 1993 OEL-UNITED KINGDOM:TWA 0.05 mg(V2O5)/m3 (dust) JAN 1993 OEL-UNITED KINGDOM:TWA 0.5 mg(V2O5)/m3 JAN 1993 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH RECOMMENDED EXPOSURE LEVEL (REL) : NIOSH REL TO VANADIUM (as V2O5), resp dust/fume-air:CL 0.05 mg/m3/15M REFERENCE : NIOSH* National Institute for Occupational Safety and Health, U.S. Dept. of Health, Education, and Welfare, Reports and Memoranda. Volume(issue)/page/year: DHHS #92-100,1992
Safety Information
[ Symbol ]:
GHS05, GHS06
[ Signal Word ]:
Danger
[ Hazard Statements ]:
H301-H314
[ Supplemental HS ]:
Reacts violently with water.
[ Precautionary Statements ]:
P280-P301 + P310-P305 + P351 + P338-P310
[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
[ Hazard Codes ]:
T:Toxic;
[ Risk Phrases ]:
R14;R25;R34
[ Safety Phrases ]:
S26-S27-S28-S36/37/39-S45
[ RIDADR ]:
UN 2443 8/PG 2
[ WGK Germany ]:
3
[ RTECS ]:
YW2975000
[ Packaging Group ]:
II
[ Hazard Class ]:
8
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Articles
Gig. Tr. Prof. Zabol. (1) , 51-2, (1985)
The gas-phase on-line production of vanadium oxytrihalides, VOX3 and their identification by infrared spectroscopy.
Spectrochim. Acta. A. Mol. Biomol. Spectrosc. 56(14) , 2693-8, (2000)
A new route has been devised, leading to the production of VOX3 molecules where X=F, Br and I by an on-line process using vanadium oxytrichloride, VOCl3 as a starting compound passed over the followin...
Aerobic oxidation of thiols to disulfides catalyzed by trichlorooxyvanadium.Chem. Pharm. Bull. 52(5) , 625-7, (2004)
Thiols were converted into disulfide by the aerobic oxidation catalyzed by trichlorooxyvanadium in the presence of molecular sieves 3A.