Vinyltrimethylsilane

Names

[ CAS No. ]:
754-05-2

[ Name ]:
Vinyltrimethylsilane

[Synonym ]:
ethenyl(trimethyl)silane
Trimethyl(vinyl)silane
EINECS 212-042-9
MFCD00008606
vinyl trimethyl silane
Vinyltrimethylsilane
Silane, ethenyltrimethyl-

Chemical & Physical Properties

[ Density]:
0.7±0.1 g/cm3

[ Boiling Point ]:
55.0±0.0 °C at 760 mmHg

[ Melting Point ]:
-132°C

[ Molecular Formula ]:
C₅H₁₂Si

[ Molecular Weight ]:
100.234

[ Flash Point ]:
-9.4±12.0 °C

[ Exact Mass ]:
100.070824

[ LogP ]:
1.77

[ Vapour Pressure ]:
253.2±0.1 mmHg at 25°C

[ Index of Refraction ]:
1.390

[ Storage condition ]:
Flammables area

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS02, GHS07, GHS08

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H225-H302-H315-H319-H335-H351

[ Precautionary Statements ]:
P210-P280-P301 + P312 + P330-P305 + P351 + P338-P370 + P378-P403 + P235

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US)

[ Hazard Codes ]:
F:Flammable;Xn:Harmful;

[ Risk Phrases ]:
R11;R22;R36/37/38

[ Safety Phrases ]:
S16-S26-S33-S36-S36/37/39

[ RIDADR ]:
UN 1993 3/PG 1

[ WGK Germany ]:
1

[ Packaging Group ]:
II

[ Hazard Class ]:
3

[ HS Code ]:
2931900090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

Customs

[ HS Code ]: 2931900090

[ Summary ]:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

Articles

Highly efficient O-silylation of alcohol with vinylsilane using a Rh(I)/HCl catalyst at room temperature.

Org. Lett. 9 , 4073, (2007)

Highly efficient O-silylation of alcohol with vinylsilane was developed using a catalyst system consisting of [(COE)(2)RhCl](2) and HCl. In this reaction, a key intermediate is chlorosilane, generated...