(trimethyl-λ4-azanyl)borane
Names
[ CAS No. ]:
75-22-9
[ Name ]:
(trimethyl-λ4-azanyl)borane
[Synonym ]:
(CH3)3NBH3
Trimethylamine borane(3)
trimethylamine*borane
MFCD00012420
BORANE-TRIMTHYLAMINE COMPLEX
BORON HYDRIDE TRIMETHYLAMINE
Trimethylamine borane (1:1)
EINECS 200-850-4
trimethylamineborane,tmab
TMAB
BORANE-TRIMETHYLAMINE
trimethylazaniumylboron
Chemical & Physical Properties
[ Density]:
0.81
[ Boiling Point ]:
172 °C(lit.)
[ Melting Point ]:
92-94 °C(lit.)
[ Molecular Formula ]:
C3H11BN
[ Molecular Weight ]:
71.93710
[ Flash Point ]:
64°C
[ Exact Mass ]:
72.09850
[ PSA ]:
12.36000
[ Water Solubility ]:
decomposes
MSDS
Toxicological Information
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- PA0525000
- CAS REGISTRY NUMBER :
- 75-22-9
- LAST UPDATED :
- 199701
- DATA ITEMS CITED :
- 5
- MOLECULAR FORMULA :
- C3-H12-B-N
- MOLECULAR WEIGHT :
- 72.97
- WISWESSER LINE NOTATION :
- 1N1&1 &B-H3
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Intraperitoneal
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 175 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Intraperitoneal
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 140 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
MUTATION DATA
- TYPE OF TEST :
- Mutation test systems - not otherwise specified
- TEST SYSTEM :
- Rodent - mouse Ascites tumor
- DOSE/DURATION :
- 100 umol/L
- REFERENCE :
- JPMSAE Journal of Pharmaceutical Sciences. (American Pharmaceutical Assoc., 2215 Constitution Ave., NW, Washington, DC 20037) V.50- 1961- Volume(issue)/page/year: 74,755,1985
Safety Information
[ Symbol ]:
GHS02, GHS07
[ Signal Word ]:
Danger
[ Hazard Statements ]:
H228-H315-H319-H335
[ Precautionary Statements ]:
P210-P261-P305 + P351 + P338
[ Hazard Codes ]:
F:Flammable;Xi:Irritant;
[ Risk Phrases ]:
R11;R36/37/38
[ Safety Phrases ]:
S14-S16-S26-S36-S36/37/39-S33
[ RIDADR ]:
UN 1325 4.1/PG 2
[ WGK Germany ]:
3
[ RTECS ]:
PA0525000
[ Packaging Group ]:
II
[ Hazard Class ]:
4.1
[ HS Code ]:
29420000
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Customs
[ HS Code ]: 29420000
Articles
J. Org. Chem. 59 , 705, (1994)
Anal. Chem. 66 , 4283, (1994)
Aldrichimica Acta 6 , 51, (1973)