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1,2,3,6-Tetrahydropyridine

Names

[ CAS No. ]:
694-05-3

[ Name ]:
1,2,3,6-Tetrahydropyridine

[Synonym ]:
Pyridine, 1,2,3,6-tetrahydro-
Pyridine, 1,2,3,6-tetrahydro- (8CI)(9CI)
MFCD00005949
T6M CUTJ
EINECS 211-766-2
1,2,3,6-Tetrahydropyridine [UN2410] [Flammable liquid]
1,2,3,6-Tetrahydropyridine

Chemical & Physical Properties

[ Density]:
0.9±0.1 g/cm3

[ Boiling Point ]:
110.9±9.0 °C at 760 mmHg

[ Melting Point ]:
−48 °C(lit.)

[ Molecular Formula ]:
C5H9N

[ Molecular Weight ]:
83.132

[ Flash Point ]:
16.1±0.0 °C

[ Exact Mass ]:
83.073502

[ PSA ]:
12.03000

[ LogP ]:
1.05

[ Vapour Pressure ]:
23.3±0.2 mmHg at 25°C

[ Index of Refraction ]:
1.455

MSDS

Safety Information

[ Symbol ]:

GHS02, GHS07

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H225-H315-H319-H335

[ Precautionary Statements ]:
P210-P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
F: Flammable;Xi: Irritant;

[ Risk Phrases ]:
R11

[ Safety Phrases ]:
S16-S26-S36/37/39

[ RIDADR ]:
UN 2410 3/PG 2

[ WGK Germany ]:
3

[ Packaging Group ]:
II

[ Hazard Class ]:
3.1

[ HS Code ]:
2933399090

Synthetic Route

Precursor & DownStream

Customs

[ HS Code ]: 2933399090

[ Summary ]:
2933399090. other compounds containing an unfused pyridine ring (whether or not hydrogenated) in the structure. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

Articles

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A new class of ammonium ylid for [2,3]-sigmatropic rearrangement reactions: ene-endo-spiro ylids.

Org. Lett. 7 , 2075, (2005)

The first examples of sigmatropic rearrangements of ene-endo-spirocyclic, tetrahydropyridine-derived ammonium ylids are reported. Thus, spiro[6.7]-ylids rearrange primarily by a [2,3]-pathway, whereas...


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Related Compounds