5-Chloro-2-methylene-1,3,3-trimethylindoline
Names
[ CAS No. ]:
6872-17-9
[ Name ]:
5-Chloro-2-methylene-1,3,3-trimethylindoline
[Synonym ]:
5-chloro-1,3,3-trimethyl-2-methylideneindole
MFCD00005814
EINECS 229-972-6
Chemical & Physical Properties
[ Density]:
1.083 g/mL at 25 °C(lit.)
[ Boiling Point ]:
139 °C / 11mmHg
[ Molecular Formula ]:
C12H14ClN
[ Molecular Weight ]:
207.69900
[ Flash Point ]:
>230 °F
[ Exact Mass ]:
207.08100
[ PSA ]:
3.24000
[ LogP ]:
3.64610
[ Index of Refraction ]:
n20/D 1.594(lit.)
MSDS
Safety Information
[ Symbol ]:
GHS07
[ Signal Word ]:
Warning
[ Hazard Statements ]:
H315-H319-H335
[ Precautionary Statements ]:
P261-P305 + P351 + P338
[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
[ Hazard Codes ]:
Xi
[ Risk Phrases ]:
R36/37/38:Irritating to eyes, respiratory system and skin .
[ Safety Phrases ]:
S26-S37/39
[ RIDADR ]:
NONH for all modes of transport
[ WGK Germany ]:
3
[ HS Code ]:
2933990090
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Customs
[ HS Code ]: 2933990090
[ Summary ]:
2933990090. heterocyclic compounds with nitrogen hetero-atom(s) only. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%
Articles
Acta Crystallogr. Sect. E Struct. Rep. Online 65(2) , o374, (2009)
Two diastereoisomers of the title compound, C(25)H(26)N(2)O, have been prepared by cyclo-addition between 1,3,3-trimethyl-2-methyl-eneindoline and C-phenyl-N-phenyl-nitrone. The stereochemistry of the...
5',6-Dichloro-1',3',3'-trimethyl-spiro-[2H-1-benzopyran-2,2'-indoline].Acta Crystallogr. Sect. E Struct. Rep. Online 64(8) , o1430-31, (2008)
In the crystal structure of the title compound, C(19)H(17)Cl(2)NO, the indoline and benzopyran ring systems are approximately perpendicular to each other. The indoline ring is in an envelope conformat...