1,2,4,5-Tetrazine,3,6-diphenyl-

Names

[ CAS No. ]:
6830-78-0

[ Name ]:
1,2,4,5-Tetrazine,3,6-diphenyl-

[Synonym ]:
3,6-diphenyl-1,2,4,5-tetrazine
MFCD00023646

Chemical & Physical Properties

[ Density]:
1.214 g/cm3

[ Boiling Point ]:
446ºC at 760 mmHg

[ Melting Point ]:
198ºC

[ Molecular Formula ]:
C₁₄H₁₀N₄

[ Molecular Weight ]:
234.25600

[ Flash Point ]:
208.7ºC

[ Exact Mass ]:
234.09100

[ PSA ]:
51.56000

[ LogP ]:
2.60060

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :: XF6863300

CHEMICAL NAME :: 1,2,4,5-Tetrazine, 3,6-diphenyl-

CAS REGISTRY NUMBER :: 6830-78-0

LAST UPDATED :: 199309

DATA ITEMS CITED :: 1

MOLECULAR FORMULA :: C14-H10-N4

MOLECULAR WEIGHT :: 234.28

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LDLo - Lowest published lethal dose

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 1 gm/kg

TOXIC EFFECTS :: Brain and Coverings - recordings from specific areas of CNS Behavioral - somnolence (general depressed activity)

REFERENCE :: RPTOAN Russian Pharmacology and Toxicology (English Translation). Translation of FATOAO. (Euromed Pub., 33, Woodlands Rd., Surbiton, Surrey, UK) V.30- 1967- Volume(issue)/page/year: 43,213,1980

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36

[ RIDADR ]:
NONH for all modes of transport

[ RTECS ]:
XF6863300

[ HS Code ]:
2933990090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

Customs

[ HS Code ]: 2933990090

[ Summary ]:
2933990090. heterocyclic compounds with nitrogen hetero-atom(s) only. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

Articles

Clicking 1,2,4,5-tetrazine and cyclooctynes with tunable reaction rates.

Chem. Commun. (Camb.) 48(12) , 1736-8, (2012)

Substituted tetrazines have been found to undergo facile inverse electron demand Diels-Alder reactions with "tunable" reaction rates.This journal is © The Royal Society of Chemistry 2012

Facile, completely regioselective 1,4-hydrogenations of C(60)-diaryltetrazine monoadducts

Org. Lett. 2(20) , 3091-4, (2000)

Thermal Diels-Alder reactions between C(60) and electron-deficient 3, 6-diaryl-1,2,4,5-tetrazines yield monoadducts possessing a diaryldihydropyridazine function nested atop the fullerene. The diaryld...

Reaction of 3, 6-diphenyl-1, 2, 4, 5-tetrazine with cis, cis-1, 5-cyclooctadiene: An attempt at preparing some dihydropyridazine derivatives. Satish S, et al.

Tetrahedron 35(2) , 277-85, (1979)