styrylboronic acid

Names

[ Name ]:
styrylboronic acid

[Synonym ]:
TRANS-B-STYRENEBORONIC ACID
[(E)-2-Phenylvinyl]boronic acid
trans-2-styrylboronic acid
TRANS-PHENYLVINYLBORONIC ACID
MFCD00963621
trans-styreneboronic acid
styrylboronic acid
trans-phenylethenyl boronic acid
dihydroxy-(E)-styrylborane
TRANS-2-PHENYLVINYLBORONIC ACID
RARECHEM AH PB 0201
Phenylethenylboronicacid
Boronic acid, B-[(E)-2-phenylethenyl]-
(E)-Styreneboronic acid

Chemical & Physical Properties

[ Density]:
1.1±0.1 g/cm3

[ Boiling Point ]:
315.9±35.0 °C at 760 mmHg

[ Melting Point ]:
146-156 °C(lit.)

[ Molecular Formula ]:
C₈H₉BO₂

[ Molecular Weight ]:
147.967

[ Flash Point ]:
144.9±25.9 °C

[ Exact Mass ]:
148.069565

[ PSA ]:
40.46000

[ LogP ]:
2.57

[ Vapour Pressure ]:
0.0±0.7 mmHg at 25°C

[ Index of Refraction ]:
1.587

[ Storage condition ]:
0-6°C

MSDS

Click to get detail MSDS

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ Hazard Codes ]:
Xi

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S37/39-S26

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2931900090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

Customs

[ HS Code ]: 2931900090

[ Summary ]:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

Articles

Rh2(II)-catalyzed intramolecular aliphatic C-H bond amination reactions using aryl azides as the N-atom source.

J. Am. Chem. Soc. 17th ed., 134 , 7262-7265, (2012)

Rhodium(II) dicarboxylate complexes were discovered to catalyze the intramolecular amination of unactivated primary, secondary, or tertiary aliphatic C-H bonds using aryl azides as the N-atom precurso...

Copper-mediated sequential cyanation of aryl C-B and arene C-H bonds using ammonium iodide and DMF.

J. Am. Chem. Soc. 5th ed., 134 , 2528-2531, (2012)

The cyanation of aromatic boronic acids, boronate esters, and borate salts was developed under copper-mediated oxidative conditions using ammonium iodide and DMF as the source of nitrogen and carbon a...

Ambient temperature synthesis of high enantiopurity N-protected peptidyl ketones by peptidyl thiol ester-boronic acid cross-coupling.

J. Am. Chem. Soc. 129 , 1132, (2007)

alpha-Amino acid thiol esters derived from N-protected mono-, di-, and tripeptides couple with aryl, pi-electron-rich heteroaryl, or alkenyl boronic acids in the presence of stoichiometric Cu(I) thiop...