N'-Isopropylidene-2-nitrobenzenesulfonohydrazide

[ Density]:
1.4±0.1 g/cm3

[ Boiling Point ]:
421.3±47.0 °C at 760 mmHg

[ Melting Point ]:
131-135ºC

[ Molecular Formula ]:
C₉H₁₁N₃O₄S

[ Molecular Weight ]:
257.266

[ Flash Point ]:
208.6±29.3 °C

[ Exact Mass ]:
257.047028

[ PSA ]:
112.73000

[ LogP ]:
1.02

[ Vapour Pressure ]:
0.0±1.0 mmHg at 25°C

[ Index of Refraction ]:
1.603

[ Storage condition ]:
<0°C

Click to get detail MSDS

[ Personal Protective Equipment ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ Hazard Codes ]:
Xi

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3.0

Click to get detail synthetic route

Precursor

DownStream

N-isopropylidene-N'-2-nitrobenzenesulfonyl hydrazine, a reagent for reduction of alcohols via the corresponding monoalkyl diazenes.

J. Org. Chem. 72 , 1838, (2007)

The reagent N-isopropylidene-N'-2-nitrobenzenesulfonyl hydrazine (IPNBSH) is used in the reduction of alcohols via the loss of dinitrogen from transiently formed monoalkyl diazene intermediates access...

A stereospecific palladium-catalyzed route to monoalkyl diazenes for mild allylic reduction.

Angew. Chem. Int. Ed. Engl. 47 , 8909, (2008)

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