2-propenylphenol

Names

[ Name ]:
2-propenylphenol

[Synonym ]:
2-propenyl-pheno
o-propenyl-pheno
o-(prop-1-enyl)phenol
2-(prop-1-enyl)phenol
2-propenyl-phenol
1-(1-propenyl)phenol
2-(1-propenyl)-pheno
(E/Z)-2-propenylphenol
Einecs 228-961-3
Phenol,o-propenyl
2-(1-Propenyl)phenol
Phenol,2-propenyl
MFCD00002248

Chemical & Physical Properties

[ Density]:
1.044 g/mL at 25ºC(lit.)

[ Boiling Point ]:
230-231ºC(lit.)

[ Melting Point ]:
-6°C

[ Molecular Formula ]:
C₉H₁₀O

[ Molecular Weight ]:
134.17500

[ Flash Point ]:
195 °F

[ Exact Mass ]:
134.07300

[ PSA ]:
20.23000

[ LogP ]:
2.42530

[ Index of Refraction ]:
n20/D 1.578(lit.)

[ Storage condition ]:
2-8℃

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :: SM8575000

CHEMICAL NAME :: Phenol, 2-propenyl-

CAS REGISTRY NUMBER :: 6380-21-8

BEILSTEIN REFERENCE NO. :: 2324090

LAST UPDATED :: 199612

DATA ITEMS CITED :: 2

MOLECULAR FORMULA :: C9-H10-O

MOLECULAR WEIGHT :: 134.19

WISWESSER LINE NOTATION :: QR B2U1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 3400 mg/kg/12W-I

TOXIC EFFECTS :: Tumorigenic - neoplastic by RTECS criteria Skin and Appendages - tumors

MUTATION DATA

TYPE OF TEST :: Sister chromatid exchange

TEST SYSTEM :: Human Lymphocyte

DOSE/DURATION :: 250 umol/L

REFERENCE :: MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 169,129,1986

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi

[ Risk Phrases ]:
36/37/38

[ Safety Phrases ]:
S26;S36/S37/S39

[ RIDADR ]:
UN 3145 8/PG 3

[ WGK Germany ]:
3

[ RTECS ]:
SM8575000

[ Packaging Group ]:
III

[ Hazard Class ]:
6.1(b)

[ HS Code ]:
2907199090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

Customs

[ HS Code ]: 2907199090

[ Summary ]:
2907199090 other monophenols VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

Articles

Reaction of ortho alkenyl-and alkylphenols with 2, 3-dichloro-5, 6-dicyanobenzoquinone (DDQ): Syntheses of 2, 2-dialkylchromenes. Cardillo G, et al.

Tetrahedron 27(10) , 1875-83, (1971)