CHLOROETHYL CHLOROFORMATE
Names
[ CAS No. ]:
627-11-2
[ Name ]:
CHLOROETHYL CHLOROFORMATE
[Synonym ]:
2-Chlorethylchlorocarbonat
2-Chloroethyl chloroformate
1-Chloroethyl chloroformate
1-Chloroethyl carbonochloridate
α-Chloroethyl chloroformate
MFCD00000646
Carbonochloridic acid, 2-chloroethyl ester
2-Chloroethyl carbonochloridate
CHLOROETHYL CHLOROFORMATE
Carbonochloridic acid, 1-chloroethyl ester
EINECS 210-982-4
Chemical & Physical Properties
[ Density]:
1.4±0.1 g/cm3
[ Boiling Point ]:
156.9±13.0 °C at 760 mmHg
[ Melting Point ]:
-70ºC BOLING
[ Molecular Formula ]:
C3H4Cl2O2
[ Molecular Weight ]:
142.969
[ Flash Point ]:
59.8±15.2 °C
[ Exact Mass ]:
141.958832
[ PSA ]:
26.30000
[ LogP ]:
1.51
[ Vapour Pressure ]:
2.8±0.3 mmHg at 25°C
[ Index of Refraction ]:
1.439
MSDS
Toxicological Information
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- LQ5950000
- CHEMICAL NAME :
- Formic acid, chloro-, 2-chloroethyl ester
- CAS REGISTRY NUMBER :
- 627-11-2
- BEILSTEIN REFERENCE NO. :
- 0506639
- LAST UPDATED :
- 199701
- DATA ITEMS CITED :
- 3
- MOLECULAR FORMULA :
- C3-H4-Cl2-O2
- MOLECULAR WEIGHT :
- 142.97
- WISWESSER LINE NOTATION :
- GVO2G
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
- TYPE OF TEST :
- LCLo - Lowest published lethal concentration
- ROUTE OF EXPOSURE :
- Inhalation
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 200 mg/m3/10M
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- NDRC** National Defense Research Committee, Office of Scientific Research and Development, Progress Report. Volume(issue)/page/year: NDCrc-132,JUN1942
Safety Information
[ Symbol ]:
GHS05, GHS06
[ Signal Word ]:
Danger
[ Hazard Statements ]:
H314-H331
[ Precautionary Statements ]:
P261-P280-P305 + P351 + P338-P310
[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
[ Hazard Codes ]:
T:Toxic;
[ Risk Phrases ]:
R23;R34
[ Safety Phrases ]:
S26-S36/37/39-S45
[ RIDADR ]:
3277
[ RTECS ]:
LQ5950000
[ Packaging Group ]:
II
[ Hazard Class ]:
6.1(a)
[ HS Code ]:
2915900090
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Customs
[ HS Code ]: 2915900090
[ Summary ]:
2915900090 other saturated acyclic monocarboxylic acids and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward) MFN tariff:5.5% General tariff:30.0%
Articles
Tetrahedron Lett. 40(42) , 7489-92, (1999)
A new approach to pyrrolophenanthridone alkaloids via allene intramolecular cycloaddition: Total synthesis of Hippadine. Hayakawa K, et al.
Tetrahedron Lett. 28(47) , 5895-98, (1987)
Enzymatic resolution of new carbonate intermediates for the synthesis of (< i> S</i>)-(+)-zopiclone. Solares LF, et al.
Tetrahedron Asymmetry 13(23) , 2577-82, (2002)