3-Butenoic acid

Names

[ CAS No. ]:
625-38-7

[ Name ]:
3-Butenoic acid

[Synonym ]:
Vinyl acetic acid
But-3-enoic acid
vinylacetic acid
3-Butenoic acid
EINECS 210-892-5
MFCD00002782
Iodoquinol Impurity 4

Biological Activity

[Description]:

3-Butenoic acid (Vinylacetic acid) can be used to synthesize bicyclic 3,6-dihydro-1,2-oxazine. Strained bicyclic 3,6-dihydro-1,2-oxazine is a reactive substrate in domino metathesis with an external alkene[1][2].

[Related Catalog]:

Research Areas >> Others

Signaling Pathways >> Others >> Others

[References]

[1]. Géraldine Calvet, et al. Domino metathesis of 3,6-dihydro-1,2-oxazine: access to isoxazolo[2,3-a]pyridin-7-ones. Org Lett. 2007 Apr 12;9(8):1485-8.

[2]. M A Casado-Rodriguez, et al. Synthesis of vinyl-terminated Au nanoprisms and nanooctahedra mediated by 3-butenoic acid: direct Au@pNIPAM fabrication with improved SERS capabilities. Nanoscale. 2016 Feb 28;8(8):4557-64.

Chemical & Physical Properties

[ Density]:
1.0±0.1 g/cm3

[ Boiling Point ]:
170.6±9.0 °C at 760 mmHg

[ Melting Point ]:
−39 °C(lit.)

[ Molecular Formula ]:
C₄H₆O₂

[ Molecular Weight ]:
86.089

[ Flash Point ]:
65.6±0.0 °C

[ Exact Mass ]:
86.036781

[ PSA ]:
37.30000

[ LogP ]:
0.54

[ Vapour Pressure ]:
0.7±0.7 mmHg at 25°C

[ Index of Refraction ]:
1.432

[ Storage condition ]:
2-8°C

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS05, GHS07

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H302-H314

[ Precautionary Statements ]:
P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
C:Corrosive;

[ Risk Phrases ]:
R34

[ Safety Phrases ]:
S26-S36/37/39-S45

[ RIDADR ]:
UN 2922 8/PG 2

[ WGK Germany ]:
2

[ Packaging Group ]:
II

[ Hazard Class ]:
8

[ HS Code ]:
2916190090

Customs

[ HS Code ]: 2916190090

[ Summary ]:
2916190090 unsaturated acyclic monocarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives。supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward)。VAT:17.0%。tax rebate rate:9.0%。MFN tariff:6.5%。general tariff:30.0%

Articles

On the Question of Site-Selective Ligand Exchange in Carboxylate-Substituted Metal Oxo Clusters.

Eur. J. Inorg. Chem. 2015 , 2889-2894, (2015)

Reaction of [Ti4Zr4O6(OBu)4(OMc)16] (OMc = methacrylate) with acetylacetone (acacH) resulted in dissection of the cluster and formation of [Ti(OBu)2(acac)2] and the smaller cluster [Ti2Zr4O4(OMc)16]. ...

Synthesis of base substituted 2-hydroxy-3-(purin-9-yl)-propanoic acids and 4-(purin-9-yl)-3-butenoic acids.

Nucleosides Nucleotides Nucleic Acids 22(12) , 2145-60, (2003)

Alkylation of 6-chloropurine and 2-amino-6-chloropurine with bromoacetaldehyde diethyl acetal afforded 6-chloro-9-(2,2-diethoxyethyl)purine (3a) and its 2-amino congener (3b). Treatment of compounds 3...

Increases in microbial nitrogen production and efficiency in vitro with three inhibitors of ruminal methanogenesis.

Can. J. Microbiol. 53(4) , 496-503, (2007)

It was hypothesized that the addition of crotonic acid or 3-butenoic acid would relieve constraints in digestibility observed when methane formation is inhibited by lumazine, propynoic acid, or ethyl ...