4-Methylbenzamide

Names

[ CAS No. ]:
619-55-6

[ Name ]:
4-Methylbenzamide

[Synonym ]:
p-toluamide
p-Methylbenzamide
4-Methylbenzamide
EINECS 210-600-6
4-methylphenylformamide
MFCD00008002
Benzamide, 4-methyl-
4-Methylbenzolcarboxamid

Chemical & Physical Properties

[ Density]:
1.1±0.1 g/cm3

[ Boiling Point ]:
270.4±19.0 °C at 760 mmHg

[ Melting Point ]:
159-162 °C

[ Molecular Formula ]:
C₈H₉NO

[ Molecular Weight ]:
135.163

[ Flash Point ]:
117.3±21.5 °C

[ Exact Mass ]:
135.068420

[ PSA ]:
43.09000

[ LogP ]:
1.20

[ Vapour Pressure ]:
0.0±0.6 mmHg at 25°C

[ Index of Refraction ]:
1.556

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :: CV5570150

CHEMICAL NAME :: Benzamide, 4-methyl-

CAS REGISTRY NUMBER :: 619-55-6

LAST UPDATED :: 199709

DATA ITEMS CITED :: 2

MOLECULAR FORMULA :: C8-H9-N-O

MOLECULAR WEIGHT :: 135.18

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Unreported

SPECIES OBSERVED :: Mammal - species unspecified

DOSE/DURATION :: 1 gm/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: PCJOAU Pharmaceutical Chemistry Journal (English Translation). Translation of KHFZAN. (Plenum Pub. Corp., 233 Spring St., New York, NY 10013) No.1- 1967- Volume(issue)/page/year: 28,335,1994

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H302-H319

[ Precautionary Statements ]:
P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xn

[ Risk Phrases ]:
22-36

[ Safety Phrases ]:
S24/25

[ RIDADR ]:
NONH for all modes of transport

[ RTECS ]:
CV5570150

[ HS Code ]:
2924299090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

Customs

[ HS Code ]: 2924299090

[ Summary ]:
2924299090. other cyclic amides (including cyclic carbamates) and their derivatives; salts thereof. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

Articles

Alumina catalyzed transformations of O-(3-oxobutyl) urethanes. Reitz A, et al.

Tetrahedron Lett. 23(7) , 751-2, (1982)