2-Nitroacetophenone
Names
[ CAS No. ]:
614-21-1
[ Name ]:
2-Nitroacetophenone
[Synonym ]:
α-Nitroacetophenone
2-Nitro-1-phenylethan-1-one
MFCD00010218
2-Nitroacetophenone
WN1VR
Ethanone, 2-nitro-1-phenyl-
2-Nitro-1-phenylethanone
Benzoylnitromethane
2-Nitro-1-phenylethanon
Chemical & Physical Properties
[ Density]:
1.2±0.1 g/cm3
[ Boiling Point ]:
298.6±23.0 °C at 760 mmHg
[ Melting Point ]:
105-107ºC
[ Molecular Formula ]:
C8H7NO3
[ Molecular Weight ]:
165.146
[ Flash Point ]:
146.9±15.4 °C
[ Exact Mass ]:
165.042587
[ PSA ]:
62.89000
[ LogP ]:
1.68
[ Vapour Pressure ]:
0.0±0.6 mmHg at 25°C
[ Index of Refraction ]:
1.545
[ Storage condition ]:
Refrigerator (+4°C)
MSDS
Safety Information
[ Symbol ]:
GHS07
[ Signal Word ]:
Warning
[ Hazard Statements ]:
H302 + H312 + H332-H315-H319-H335
[ Precautionary Statements ]:
P261-P280-P305 + P351 + P338
[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves
[ Hazard Codes ]:
Xn: Harmful;
[ Risk Phrases ]:
R20/21/22
[ Safety Phrases ]:
26-37/39
[ RIDADR ]:
NONH for all modes of transport
[ WGK Germany ]:
3
[ HS Code ]:
2914700090
Synthetic Route
Customs
[ HS Code ]: 2914700090
[ Summary ]:
HS: 2914700090 halogenated, sulphonated, nitrated or nitrosated derivatives of ketones and quinones, whether or not with other oxygen function Tax rebate rate:9.0% Supervision conditions:none VAT:17.0% MFN tariff:5.5% General tariff:30.0%
Articles
J. Org. Chem. 62(23) , 8162-8170, (1997)
The replacement of a hydrogen in nitromethane and in phenylnitromethane by the PhCO group has a strong acidifying effect, i.e., PhCOCH(2)NO(2), 5, is 5.8, 6.6, and 8.6 pK(a) units more acidic than CH(...