3-(Trimethylsilyl)propynoic acid

[ Density]:
1.0±0.1 g/cm3

[ Boiling Point ]:
219.1±9.0 °C at 760 mmHg

[ Melting Point ]:
47-49 °C(lit.)

[ Molecular Formula ]:
C₆H₁₀O₂Si

[ Molecular Weight ]:
142.228

[ Flash Point ]:
86.3±18.7 °C

[ Exact Mass ]:
142.045013

[ PSA ]:
37.30000

[ LogP ]:
2.19

[ Vapour Pressure ]:
0.0±0.9 mmHg at 25°C

[ Index of Refraction ]:
1.452

Click to get detail MSDS

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi: Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

Precursor

DownStream

Trimethylsilyl-directed 1,3-dipolar cycloaddition reactions in the solid-phase synthesis of 1,2,3-triazoles.

Org. Lett. 7(8) , 1469-72, (2005)

[reaction: see text] A regioselective method for the preparation of 1,5-trisubstituted 1H-1,2,3-triazoles via a 1,3-dipolar cycloaddition of 1-trimethylsilylacetylenes with organoazides is described. ...

One-Pot Synthesis of 3-(Trimethylsilyl) propynamides. Medvedeva AS, et al.

Russ. J. Org. Chem. 46(10) , 1466-1470, (2010)

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