Methyl methoxyacetate

Names

[ Name ]:
Methyl methoxyacetate

[Synonym ]:
Acetic acid, 2-methoxy-, methyl ester
Methyl methoxyacetate
Glyoxal 1-(dimethyl acetal)
EINECS 421-890-0
Acetaldehyde, 2,2-dimethoxy-
Glyoxal dimethyl acetal
Dimethoxyacetaldehyde
2,2-dimethoxyacetaldehyde
MFCD00134410

Chemical & Physical Properties

[ Density]:
1.0±0.1 g/cm3

[ Boiling Point ]:
63.9±20.0 °C at 760 mmHg

[ Molecular Formula ]:
C₄H₈O₃

[ Molecular Weight ]:
104.104

[ Flash Point ]:
-18.4±8.2 °C

[ Exact Mass ]:
104.047340

[ PSA ]:
35.53000

[ LogP ]:
-0.13

[ Vapour Pressure ]:
167.9±0.1 mmHg at 25°C

[ Index of Refraction ]:
1.378

[ Storage condition ]:
2-8°C

[ Water Solubility ]:
Fully miscible in water.

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H317

[ Precautionary Statements ]:
P280

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R43

[ Safety Phrases ]:
S24-S37

[ RIDADR ]:
UN 2398 3/PG 2

[ WGK Germany ]:
-

[ HS Code ]:
2912499000

Synthetic Route

Click to get detail synthetic route

Customs

[ HS Code ]: 2912499000

[ Summary ]:
2912499000. other aldehyde-ethers, aldehyde-phenols and aldehydes with other oxygen function. VAT:17.0%. Tax rebate rate:9.0%. . MFN tariff:5.5%. General tariff:30.0%

Articles

Catalyst-Free Aldol Additions of 1,3-Dicarbonyl Compounds. Rohr K and Mahrwald R.

Adv. Synth. Catal. 350(18) , 2877-2880, (2008)

Synthesis and activity of isoxazoline vinyl ester pseudopeptides as proteasome inhibitors. Marastoni M, et al.

J. Pept. Sci. 20(4) , 258-265, (2014)

Design and synthesis of Pictet-Spengler condensation products that exhibit oncogenic-RAS synthetic lethality and induce non-apoptotic cell death. Skouta R, et al.

Bioorg. Med. Chem. Lett. 22(17) , 5707-5713, (2012)