2,3-Dibromopropene

Names

[ CAS No. ]:
513-31-5

[ Name ]:
2,3-Dibromopropene

[Synonym ]:
2,3-dibromoprop-1-ene
Glycine, sulfate (3:1)
2,3-DibroMopropene
EINECS 208-155-8
Glycine sulfate (3:1)
MFCD00000211
Triglycine sulfate
2-Bromoallyl Bromide

Chemical & Physical Properties

[ Density]:
1.934 g/mL at 25 °C(lit.)

[ Boiling Point ]:
42-44 °C17 mm Hg(lit.)

[ Molecular Formula ]:
C₆H₁₇N₃O₁₀S

[ Molecular Weight ]:
323.278

[ Flash Point ]:
178 °F

[ Exact Mass ]:
323.063477

[ LogP ]:
2.28990

[ Index of Refraction ]:
n20/D 1.544(lit.)

[ Water Solubility ]:
insoluble

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :: UC8200000

CHEMICAL NAME :: 1-Propene, 2,3-dibromo-

CAS REGISTRY NUMBER :: 513-31-5

BEILSTEIN REFERENCE NO. :: 0878169

LAST UPDATED :: 199710

DATA ITEMS CITED :: 4

MOLECULAR FORMULA :: C3-H4-Br2

MOLECULAR WEIGHT :: 199.89

WISWESSER LINE NOTATION :: E1YEU1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intravenous

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 100 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

MUTATION DATA

TYPE OF TEST :: Mutation in microorganisms

TEST SYSTEM :: Bacteria - Salmonella typhimurium

DOSE/DURATION :: 100 nmol/plate

REFERENCE :: ENMUDM Environmental Mutagenesis. (New York, NY) V.1-9, 1979-87. For publisher information, see EMMUEG. Volume(issue)/page/year: 2,59,1980

Safety Information

[ Symbol ]:

GHS05, GHS07

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H302 + H332-H318

[ Precautionary Statements ]:
P280-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S39-S37/39

[ RIDADR ]:
2810

[ WGK Germany ]:
3

[ RTECS ]:
UC8200000

[ Packaging Group ]:
III

[ Hazard Class ]:
6.1(b)

[ HS Code ]:
29033036

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

Customs

[ HS Code ]: 2903399090

[ Summary ]:
2903399090. brominated,fluorinated or iodinated derivatives of acyclic hydrocarbons. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0%

Articles

Mutagenicity of 2- and 3-carbon halogenated compounds in the Salmonella/mammalian-microsome test.

Environ. Mutagen. 2(1) , 59-66, (1980)

Short-chain, 2- and 3- carbon halogenated hydrocarbons were tested for mutagenicity for Salmonella typhimurium strain TA 100 both with and without the presence of S-9. Without exception, all brominate...

Kinetics and products of hydrolysis of 1,2-dibromo-3-chloropropane.

Environ. Sci. Technol. 16(9) , 627-32, (1982)

Synthesis of 2,5-Diaryl-1,5-dienes from Allylic Bromides Using Visible-Light Photoredox Catalysis.

J. Org. Chem. 80 , 11388-97, (2015)

Visible-light photoreductive coupling of 2-arylallyl bromides in the presence of the photocatalyst Ru(bpy)3(PF6)2, a Hantzsch ester, and i-Pr2NEt gives 2,5-diaryl-1,5-dienes in high yield. This method...