3-Furaldehyde

Names

[ CAS No. ]:
498-60-2

[ Name ]:
3-Furaldehyde

[Synonym ]:
MFCD00010424
3-Furaldehyde
3-Furancarboxaldehyde
furan-3-carbaldehyde

Biological Activity

[Description]:

3-Furaldehyde is a member of furans and an aldehyde, and can be used to synthesize the neoclerodane diterpene Salvinorin A[1][2].

[Related Catalog]:

Research Areas >> Others

Signaling Pathways >> Others >> Others

[References]

[1]. Nihal Kuş, et al. Photoisomerization and photochemistry of matrix-isolated 3-furaldehyde. J Phys Chem A. 2010 Dec 2;114(47):12427-36.

[2]. Yuzhou Wang, et al. Total Synthesis of the Neoclerodane Diterpene Salvinorin A via an Intramolecular Diels-Alder Strategy. Org Lett. 2018 Jun 1;20(11):3418-3421.

Chemical & Physical Properties

[ Density]:
1.1±0.1 g/cm3

[ Boiling Point ]:
145.3±0.0 °C at 760 mmHg

[ Molecular Formula ]:
C₅H₄O₂

[ Molecular Weight ]:
96.084

[ Flash Point ]:
48.3±0.0 °C

[ Exact Mass ]:
96.021126

[ PSA ]:
30.21000

[ LogP ]:
0.51

[ Vapour Pressure ]:
4.9±0.2 mmHg at 25°C

[ Index of Refraction ]:
1.515

[ Storage condition ]:
2-8°C

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS02, GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H226-H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R10;R36/37/38

[ Safety Phrases ]:
S26-S36-S45-S36/37-S16

[ RIDADR ]:
UN 1989 3/PG 3

[ WGK Germany ]:
3

[ Packaging Group ]:
III

[ Hazard Class ]:
3

[ HS Code ]:
2932190090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

Customs

[ HS Code ]: 2932190090

[ Summary ]:
2932190090 other compounds containing an unfused furan ring (whether or not hydrogenated) in the structure VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:20.0%

Articles

Paternò-Büchi reaction between furan and heterocyclic aldehydes: oxetane formation vs. metathesis.

Photochem. Photobiol. Sci. 9(8) , 1134-8, (2010)

The photochemical reaction of 2-substituted heterocyclic aldehydes with furan gave the corresponding exo oxetane derivatives through the excited triplet state. However, in situ the oxetane derivatives...