2-Fluoro-4-nitroanisole

[ Density]:
1.321 g/cm3

[ Boiling Point ]:
277.2ºC at 760 mmHg

[ Melting Point ]:
103-105 °C(lit.)

[ Molecular Formula ]:
C₇H₆FNO₃

[ Molecular Weight ]:
171.12600

[ Flash Point ]:
121.4ºC

[ Exact Mass ]:
171.03300

[ PSA ]:
55.05000

[ LogP ]:
2.26570

[ Vapour Pressure ]:
0.000519mmHg at 25°C

[ Index of Refraction ]:
1.552

Click to get detail MSDS

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S37/39

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2909309090

Click to get detail synthetic route

Precursor

DownStream

[ HS Code ]: 2909309090

[ Summary ]:
2909309090 other aromatic ethers and their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

The element effect and nucleophilicity in nucleophilic aromatic photosubstitution (SN2Ar*). Local atom effects as mechanistic probes of very fast reactions.

J. Org. Chem. 73(5) , 1925-34, (2008)

Photoreactions of 4-nitroanisole and the 2-halo-4-nitroanisoles (halogen = F, Cl, Br, and I) with the nucleophiles hydroxide ion and pyridine have been investigated quantitatively to extend the findin...

The photosubstitution of 2-fluoro-4-nitroanisole with n-hexylamine. Evidence of two different triplet excited states in a dual mechanistic pathway. Pleixats R and Marquet J.

Tetrahedron 46(4) , 1343-52, (1990)

The Search for Biochemical Photoprobes. III. The Photoreactions of 4-Nitroveratrole and 2-Fluoro-4-nitroanisole with Bovine Pancreatic Ribonuclease A and with Model Nucleophiles. Marquet J, et al.

Tetrahedron 49(6) , 1297-1306, (1993)

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