3-Bromo-4-fluorotoluene
Names
[ CAS No. ]:
452-62-0
[ Name ]:
3-Bromo-4-fluorotoluene
[Synonym ]:
3-Brom-4-fluor-toluol
Benzene,2-bromo-1-fluoro-4-methyl
3-Bromo-4-flurotoluene
2-bromo-1-fluoro-4-methylbenzole
3-bromo-4-fluoro-toluene
2-Bromo-1-fluoro-4-methylbenzene
3-Bromo-4-fluorotolu
1-bromo-2-fluoro-5-methylbenzene
MFCD00040827
EINECS 207-201-4
FR BE D1
5-methyl-2-fluorobromobenzene
3-Bromo-4-fluorotoluene
Benzene, 2-bromo-1-fluoro-4-methyl-
Chemical & Physical Properties
[ Density]:
1.5±0.1 g/cm3
[ Boiling Point ]:
169.2±0.0 °C at 760 mmHg
[ Molecular Formula ]:
C7H6BrF
[ Molecular Weight ]:
189.025
[ Flash Point ]:
73.3±0.0 °C
[ Exact Mass ]:
187.963684
[ LogP ]:
3.41
[ Vapour Pressure ]:
2.1±0.3 mmHg at 25°C
[ Index of Refraction ]:
1.527
MSDS
Safety Information
[ Symbol ]:
GHS07
[ Signal Word ]:
Warning
[ Hazard Statements ]:
H315-H319-H335
[ Precautionary Statements ]:
P261-P305 + P351 + P338
[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
[ Hazard Codes ]:
Xi:Irritant
[ Risk Phrases ]:
R36/37/38
[ Safety Phrases ]:
S26-S36/37/39
[ WGK Germany ]:
3
[ HS Code ]:
2903999090
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Customs
[ HS Code ]: 2903999090
[ Summary ]:
2903999090 halogenated derivatives of aromatic hydrocarbons VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%
Articles
Bioconjug. Chem. 7(1) , 102-7, (1996)
With 3-bromo-4-fluorotoluene as starting material, [4-fluoro-3-(trimethylsilyl)benzyl]guanidine was prepared in five steps in 1.5% overall yield. Radioiodination of this silicon precursor using N-chlo...
New syntheses of benzobarrelenes. Pu L and Grubbs RH.J. Org. Chem. 59(6) , 1351-53, (1994)