2-Bromo-p-toluidine
Names
[ CAS No. ]:
583-68-6
[ Name ]:
2-Bromo-p-toluidine
[Synonym ]:
2-Bromo-4-methylbenzenamine
p-Toluidine, 2-bromo-
o-Bromo-p-toluidine
EINECS 209-515-7
ZR BE D1
2-Bromo-4-toluidine
2-Bromo-4-methylanil
2-bromotoluidine
2-bromo-4-methylbenzeneamine
3-bromo-4-aminotoluene
2-bromo-p-toluidin
2-bromo-4-methyl-phenylamine
2-Bromo-4-methylaniline
4-AMINO-3-BROMTOLUOL
MFCD00007635
Benzenamine, 2-bromo-4-methyl-
4-methyl-2-bromoaniline
2-bromo-4-methyl-aniline
p-Toluidine,2-bromo
2-Bromo-p-toluid
2-BROMO-P-TOLUIDINE
Chemical & Physical Properties
[ Density]:
1.5±0.1 g/cm3
[ Boiling Point ]:
240.0±0.0 °C at 760 mmHg
[ Melting Point ]:
14-16 °C(lit.)
[ Molecular Formula ]:
C7H8BrN
[ Molecular Weight ]:
186.049
[ Flash Point ]:
101.9±21.8 °C
[ Exact Mass ]:
184.984009
[ PSA ]:
26.02000
[ LogP ]:
2.65
[ Vapour Pressure ]:
0.0±0.4 mmHg at 25°C
[ Index of Refraction ]:
1.609
MSDS
Toxicological Information
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- XU4300000
- CHEMICAL NAME :
- p-Toluidine, 2-bromo-
- CAS REGISTRY NUMBER :
- 583-68-6
- LAST UPDATED :
- 199707
- DATA ITEMS CITED :
- 2
- MOLECULAR FORMULA :
- C7-H8-Br-N
- MOLECULAR WEIGHT :
- 186.07
- WISWESSER LINE NOTATION :
- ZR BE D1
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
MUTATION DATA
- TYPE OF TEST :
- Mutation in microorganisms
- TEST SYSTEM :
- Bacteria - Salmonella typhimurium
- DOSE/DURATION :
- 1 umol/plate
- REFERENCE :
- MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 77,317,1980
Safety Information
[ Symbol ]:
GHS06
[ Signal Word ]:
Danger
[ Hazard Statements ]:
H301 + H311 + H331
[ Precautionary Statements ]:
P261-P280-P301 + P310-P311
[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
[ Hazard Codes ]:
T:Toxic;
[ Risk Phrases ]:
R23/24/25
[ Safety Phrases ]:
S36/37/39-S45-S26
[ RIDADR ]:
UN 2810 6.1/PG 3
[ WGK Germany ]:
3
[ RTECS ]:
XU4300000
[ Packaging Group ]:
III
[ Hazard Class ]:
6.1
[ HS Code ]:
29214300
Precursor & DownStream
Precursor
DownStream
Customs
[ HS Code ]: 2921430090
[ Summary ]:
HS:2921430090 toluidines and their derivatives; salts thereof VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%
Articles
Tetrahedron 62(19) , 4676-4684, (2006)
Synthesis of 7H-indolo [2, 3-c] quinolines: study of the Pd-catalyzed intramolecular arylation of 3-(2-bromophenylamino) quinolines under microwave irradiation. Koubachi J, et al.
Tetrahedron 66(10) , 1937-1946, (2010)
Synthesis and reactivity of ortho-palladated arylcarbodiimides and aryl isothiocyanates. Formation of C-palladated quinazolines. Synthesis of 2-aminoquinolines. Vicente J, et al.
Organometallics 23(20) , 4711-4722, (2004)