2-Bromo-p-toluidine

Names

[ CAS No. ]:
583-68-6

[ Name ]:
2-Bromo-p-toluidine

[Synonym ]:
2-Bromo-4-methylbenzenamine
p-Toluidine, 2-bromo-
o-Bromo-p-toluidine
EINECS 209-515-7
ZR BE D1
2-Bromo-4-toluidine
2-Bromo-4-methylanil
2-bromotoluidine
2-bromo-4-methylbenzeneamine
3-bromo-4-aminotoluene
2-bromo-p-toluidin
2-bromo-4-methyl-phenylamine
2-Bromo-4-methylaniline
4-AMINO-3-BROMTOLUOL
MFCD00007635
Benzenamine, 2-bromo-4-methyl-
4-methyl-2-bromoaniline
2-bromo-4-methyl-aniline
p-Toluidine,2-bromo
2-Bromo-p-toluid
2-BROMO-P-TOLUIDINE

Chemical & Physical Properties

[ Density]:
1.5±0.1 g/cm3

[ Boiling Point ]:
240.0±0.0 °C at 760 mmHg

[ Melting Point ]:
14-16 °C(lit.)

[ Molecular Formula ]:
C₇H₈BrN

[ Molecular Weight ]:
186.049

[ Flash Point ]:
101.9±21.8 °C

[ Exact Mass ]:
184.984009

[ PSA ]:
26.02000

[ LogP ]:
2.65

[ Vapour Pressure ]:
0.0±0.4 mmHg at 25°C

[ Index of Refraction ]:
1.609

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :: XU4300000

CHEMICAL NAME :: p-Toluidine, 2-bromo-

CAS REGISTRY NUMBER :: 583-68-6

LAST UPDATED :: 199707

DATA ITEMS CITED :: 2

MOLECULAR FORMULA :: C7-H8-Br-N

MOLECULAR WEIGHT :: 186.07

WISWESSER LINE NOTATION :: ZR BE D1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

MUTATION DATA

TYPE OF TEST :: Mutation in microorganisms

TEST SYSTEM :: Bacteria - Salmonella typhimurium

DOSE/DURATION :: 1 umol/plate

REFERENCE :: MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 77,317,1980

Safety Information

[ Symbol ]:

GHS06

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H301 + H311 + H331

[ Precautionary Statements ]:
P261-P280-P301 + P310-P311

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
T:Toxic;

[ Risk Phrases ]:
R23/24/25

[ Safety Phrases ]:
S36/37/39-S45-S26

[ RIDADR ]:
UN 2810 6.1/PG 3

[ WGK Germany ]:
3

[ RTECS ]:
XU4300000

[ Packaging Group ]:
III

[ Hazard Class ]:
6.1

[ HS Code ]:
29214300

Precursor & DownStream

Precursor

DownStream

Customs

[ HS Code ]: 2921430090

[ Summary ]:
HS:2921430090 toluidines and their derivatives; salts thereof VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

Articles

Synthesis of 7H-indolo [2, 3-c] quinolines: study of the Pd-catalyzed intramolecular arylation of 3-(2-bromophenylamino) quinolines under microwave irradiation. Hostyn S, et al.

Tetrahedron 62(19) , 4676-4684, (2006)

Synthesis of 7H-indolo [2, 3-c] quinolines: study of the Pd-catalyzed intramolecular arylation of 3-(2-bromophenylamino) quinolines under microwave irradiation. Koubachi J, et al.

Tetrahedron 66(10) , 1937-1946, (2010)

Synthesis and reactivity of ortho-palladated arylcarbodiimides and aryl isothiocyanates. Formation of C-palladated quinazolines. Synthesis of 2-aminoquinolines. Vicente J, et al.

Organometallics 23(20) , 4711-4722, (2004)