Methyl 2-bromoacrylate
Names
[ CAS No. ]:
4519-46-4
[ Name ]:
Methyl 2-bromoacrylate
[Synonym ]:
methyl 2-bromopropenoate
2-Brom-acrylsaeure-methylester
MFCD08276754
2-Propenoic acid,2-bromo-,methyl ester
2-Propenoic acid, 2-bromo-, methyl ester
Methyl 2-bromoacrylate
2-bromo-acrylic acid methyl ester
Methyl |A-bromoacrylate
Methyl-(2-brom-acrylat)
Methylalpha-bromoacrylate
monobromo methyl acrylate
Chemical & Physical Properties
[ Density]:
1.6±0.1 g/cm3
[ Boiling Point ]:
139.7±13.0 °C at 760 mmHg
[ Molecular Formula ]:
C4H5BrO2
[ Molecular Weight ]:
164.985
[ Flash Point ]:
38.3±19.8 °C
[ Exact Mass ]:
163.947281
[ PSA ]:
26.30000
[ LogP ]:
1.11
[ Vapour Pressure ]:
6.4±0.3 mmHg at 25°C
[ Index of Refraction ]:
1.471
[ Storage condition ]:
-20°C
MSDS
Safety Information
[ Symbol ]:
GHS02, GHS07
[ Signal Word ]:
Warning
[ Hazard Statements ]:
H226-H315-H319-H335
[ Precautionary Statements ]:
P261-P305 + P351 + P338
[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
[ Hazard Codes ]:
Xi
[ Risk Phrases ]:
36/37/38
[ Safety Phrases ]:
26-36
[ RIDADR ]:
UN 1993 3/PG 3
[ HS Code ]:
2916190090
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Customs
[ HS Code ]: 2916190090
[ Summary ]:
2916190090 unsaturated acyclic monocarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives。supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward)。VAT:17.0%。tax rebate rate:9.0%。MFN tariff:6.5%。general tariff:30.0%
Articles
Eur. Polym. J. 26(2) , 227-231, (1990)
1,2,2-tribromocyclopropanecarboxylic acid and derivatives—Valuable intermediates for four carbon cyclopropane and cyclopropene synthons Al Dulayymi AR, et al.
Tetrahedron 52(10) , 3409-3424, (1996)
A Novel Synthesis of Methyl Acrylate-α-d and 1H Nuclear Magnetic Resonance Spectra of Its Alternating Copolymers. Yokota K, et al.
Polymer J. 12(3) , 177-181, (1980)