2-(Bromovinyl)Trimethylsilane

[ Density]:
1.167 g/mL at 25 °C(lit.)

[ Boiling Point ]:
50-51 °C52 mm Hg(lit.)

[ Molecular Formula ]:
C₅H₁₁BrSi

[ Molecular Weight ]:
179.13000

[ Flash Point ]:
85 °F

[ Exact Mass ]:
177.98100

[ LogP ]:
2.77240

[ Index of Refraction ]:
n20/D 1.466(lit.)

[ Storage condition ]:
2-8°C

[ Symbol ]:

GHS02, GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H226-H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi

[ Risk Phrases ]:
10-36/37/38

[ Safety Phrases ]:
26

[ RIDADR ]:
UN 1993 3/PG 3

[ WGK Germany ]:
3

[ HS Code ]:
2931900090

Click to get detail synthetic route

Precursor

DownStream

[ HS Code ]: 2931900090

[ Summary ]:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

Palladium-Catalyzed Cross-Coupling Syntheses of Benzotriazolyl Enynes and a General Route to Enynyl Ketones and Alkynyl Ketones.

J. Org. Chem. 62(23) , 8201-8204, (1997)

A new general route to conjugated enynyl ketones was developed based on a two-step procedure. First, palladium-catalyzed cross-coupling reactions of 1-(benzotriazol-1-yl)propargyl ethyl ether (3) and ...

Ligand effects on Negishi couplings of alkenyl halides.

Org. Lett. 13(15) , 3818-21, (2011)

Negishi couplings at olefinic centers do not always occur with the anticipated maintenance of stereochemistry. The source of erosion has been traced to the ligand, and a modified method has been devel...

Spiro [2.4] hepta-1, 4, 6-triene Billups WE, et al.

J. Am. Chem. Soc. 116(14) , 6463, (1994)

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