3-Chloro-2-butanone
Names
[ CAS No. ]:
4091-39-8
[ Name ]:
3-Chloro-2-butanone
[Synonym ]:
EINECS 223-834-9
3-Chloro-2-butanone
MFCD00000865
1-Acetyl-1-Chloroethane
2-Butanone, 3-chloro-
3-chlorobutan-2-one
1-Chloroethyl Methyl Ketone
Chemical & Physical Properties
[ Density]:
1.0±0.1 g/cm3
[ Boiling Point ]:
114.7±8.0 °C at 760 mmHg
[ Melting Point ]:
<-60ºC
[ Molecular Formula ]:
C4H7ClO
[ Molecular Weight ]:
106.551
[ Flash Point ]:
21.1±0.0 °C
[ Exact Mass ]:
106.018539
[ PSA ]:
17.07000
[ LogP ]:
0.77
[ Vapour Pressure ]:
19.7±0.2 mmHg at 25°C
[ Index of Refraction ]:
1.406
[ Water Solubility ]:
3 g/100 mL
MSDS
Toxicological Information
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- EL7062000
- CHEMICAL NAME :
- 2-Butanone, 3-chloro-
- CAS REGISTRY NUMBER :
- 4091-39-8
- LAST UPDATED :
- 199712
- DATA ITEMS CITED :
- 2
- MOLECULAR FORMULA :
- C4-H7-Cl-O
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Unreported
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 810 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- TOVEFN Toksikologicheskii Vestnik. (18-20 Vadkovskii per. Moscow, 101479, Russia) History Unknown Volume(issue)/page/year: (2),34,1996
Safety Information
[ Symbol ]:
GHS02, GHS07
[ Signal Word ]:
Warning
[ Hazard Statements ]:
H226-H302
[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
[ Hazard Codes ]:
Xn:Harmful;
[ Risk Phrases ]:
R10;R20/21/22;R36/37/38
[ Safety Phrases ]:
S16-S36/37/39-S26
[ RIDADR ]:
UN 1224 3/PG 3
[ WGK Germany ]:
3
[ RTECS ]:
EL7062000
[ Packaging Group ]:
III
[ Hazard Class ]:
3
[ HS Code ]:
2942000000
Precursor & DownStream
Precursor
DownStream
Customs
[ HS Code ]: 2914700090
[ Summary ]:
HS: 2914700090 halogenated, sulphonated, nitrated or nitrosated derivatives of ketones and quinones, whether or not with other oxygen function Tax rebate rate:9.0% Supervision conditions:none VAT:17.0% MFN tariff:5.5% General tariff:30.0%
Articles
Appl. Environ. Microbiol. 69(1) , 419-26, (2003)
The 4-hydroxyacetophenone monooxygenase (HAPMO) from Pseudomonas fluorescens ACB catalyzes NADPH- and oxygen-dependent Baeyer-Villiger oxidation of 4-hydroxyacetophenone to the corresponding acetate e...
Synthesis and activity of ruthenium olefin metathesis catalysts coordinated with thiazol-2-ylidene ligands.J. Am. Chem. Soc. 130(7) , 2234-45, (2008)
A new family of ruthenium-based olefin metathesis catalysts bearing a series of thiazole-2-ylidene ligands has been prepared. These complexes are readily accessible in one step from commercially avail...
Reaction of α-chloroketones with 1, 4-dianion of acetophenone n-ethoxy-carbonylhydrazone. Matsumura N, et al.Tetrahedron Lett. 25(40) , 4529-32, (1984)