Methyl 5-chloro-2-hydroxybenzoate

Names

[ Name ]:
Methyl 5-chloro-2-hydroxybenzoate

[Synonym ]:
Salicylic acid, 5-chloro-, methyl ester
MFCD00016461
Benzoic acid, 5-chloro-2-hydroxy-, methyl ester
Methyl 5-chloro-2-hydroxybenzoate
EINECS 223-778-5
Salicylic acid, 5-chloro-, methyl ester (8CI)

Chemical & Physical Properties

[ Density]:
1.4±0.1 g/cm3

[ Boiling Point ]:
260.5±20.0 °C at 760 mmHg

[ Melting Point ]:
46-50 °C(lit.)

[ Molecular Formula ]:
C₈H₇ClO₃

[ Molecular Weight ]:
186.592

[ Flash Point ]:
111.4±21.8 °C

[ Exact Mass ]:
186.008377

[ PSA ]:
46.53000

[ LogP ]:
3.24

[ Vapour Pressure ]:
0.0±0.6 mmHg at 25°C

[ Index of Refraction ]:
1.564

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36-S37/39

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2918290000

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

Customs

[ HS Code ]: 2918290000

[ Summary ]:
HS: 2918290000 other carboxylic acids with phenol function but without other oxygen function, their anhydrides, halides, peroxides, peroxyacids and their derivatives Tax rebate rate:9.0% Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward) VAT:17.0% MFN tariff:6.5% General tariff:30.0%

Articles

411. Some derivatives of diphenylamine and a new synthesis of N-arylanthranilic acids and of acridones. Jamison MM and Turner EE.

J. Chem. Soc. , 1954-59, (1937)

Halogenosalicylohydroxamic Acids. I. Dihalogenosalicylohydroxamic Acids. DUDA H, et al.

Bulletin de l'Academie Polonaise des Sciences, Serie des Sciences Chimiques 13(5) , 341-7, (1965)