Methyl 3-methoxypropanoate
Names
[ CAS No. ]:
3852-09-3
[ Name ]:
Methyl 3-methoxypropanoate
[Synonym ]:
methyl 3-methoxypropionate
Propanoic acid, 3-methoxy-, methyl ester
Methyl 3-methoxypropanoate
3-Methoxypropionic Acid Methyl Ester
EINECS 223-358-1
MFCD00059085
Methyl β-methoxypropionate
Chemical & Physical Properties
[ Density]:
1.0±0.1 g/cm3
[ Boiling Point ]:
143.6±13.0 °C at 760 mmHg
[ Molecular Formula ]:
C5H10O3
[ Molecular Weight ]:
118.131
[ Flash Point ]:
43.5±11.4 °C
[ Exact Mass ]:
118.062996
[ PSA ]:
35.53000
[ LogP ]:
0.19
[ Vapour Pressure ]:
5.3±0.3 mmHg at 25°C
[ Index of Refraction ]:
1.391
[ Storage condition ]:
Flammables area
MSDS
Toxicological Information
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- UF5274000
- CHEMICAL NAME :
- Propionic acid, 3-methoxy-, methyl ester
- CAS REGISTRY NUMBER :
- 3852-09-3
- BEILSTEIN REFERENCE NO. :
- 1744829
- LAST UPDATED :
- 199712
- DATA ITEMS CITED :
- 6
- MOLECULAR FORMULA :
- C5-H10-O3
- MOLECULAR WEIGHT :
- 118.15
- WISWESSER LINE NOTATION :
- 1OV2O1
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
- TYPE OF TEST :
- LDLo - Lowest published lethal dose
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 1700 mg/kg
- TOXIC EFFECTS :
- Behavioral - muscle weakness Behavioral - ataxia
- REFERENCE :
- EPASR* United States Environmental Protection Agency, Office of Pesticides and Toxic Substances. (U.S. Environmental Protection Agency, 401 M St., SW, Washington, DC 20460) History unknown. Volume(issue)/page/year: 8EHQ-0486-0599
- TYPE OF TEST :
- LCLo - Lowest published lethal concentration
- ROUTE OF EXPOSURE :
- Inhalation
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 3656 ppm/6H
- TOXIC EFFECTS :
- Behavioral - muscle weakness Behavioral - ataxia
- REFERENCE :
- EPASR* United States Environmental Protection Agency, Office of Pesticides and Toxic Substances. (U.S. Environmental Protection Agency, 401 M St., SW, Washington, DC 20460) History unknown. Volume(issue)/page/year: 8EHQ-0486-0599
- TYPE OF TEST :
- LC50 - Lethal concentration, 50 percent kill
- ROUTE OF EXPOSURE :
- Inhalation
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 40 gm/m3
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 18(3),48,1974
Safety Information
[ Symbol ]:
GHS02, GHS07
[ Signal Word ]:
Warning
[ Hazard Statements ]:
H226-H315-H319-H335
[ Precautionary Statements ]:
P261-P305 + P351 + P338
[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
[ Hazard Codes ]:
Xi:Irritant;
[ Risk Phrases ]:
R10;R36/37/38
[ Safety Phrases ]:
S26-S36-S37/39
[ RIDADR ]:
UN 3272 3/PG 3
[ WGK Germany ]:
3
[ RTECS ]:
UF5274000
[ Packaging Group ]:
III
[ Hazard Class ]:
3.2
[ HS Code ]:
2918990090
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Customs
[ HS Code ]: 2918990090
[ Summary ]:
2918990090. other carboxylic acids with additional oxygen function and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%
Articles
ChemBioChem. 7(11) , 1745-9, (2006)
One of the commercial methods for preparing enantiopure amines is lipase-catalyzed kinetic resolution, although lipases catalyze aminolysis with only low activity. Interestingly, in 1997 Balkenhohl et...
A Novel Alicyclic Polymers for 193nm Single Layer Resist Materials Jung J-C, et al.J. Photopolym. Sci. Technol. 11(3) , 481-88, (1998)