Methyl 3-butenoate

[ Density]:
0.939

[ Boiling Point ]:
112 ºC

[ Molecular Formula ]:
C₅H₈O₂

[ Molecular Weight ]:
100.116

[ Flash Point ]:
20 ºC

[ Exact Mass ]:
100.052429

[ PSA ]:
26.30000

[ LogP ]:
1.00

[ Vapour Pressure ]:
57.3±0.2 mmHg at 25°C

[ Index of Refraction ]:
1.402

[ Storage condition ]:
2-8°C

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[ Symbol ]:

GHS02

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H225

[ Precautionary Statements ]:
P210

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
F: Flammable;

[ Risk Phrases ]:
R11

[ Safety Phrases ]:
16

[ RIDADR ]:
UN 3272

[ Packaging Group ]:
II

[ Hazard Class ]:
3.1

[ HS Code ]:
2916190090

Precursor

DownStream

[ HS Code ]: 2916190090

[ Summary ]:
2916190090 unsaturated acyclic monocarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives。supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward)。VAT:17.0%。tax rebate rate:9.0%。MFN tariff:6.5%。general tariff:30.0%

Iron Carbonyl-Promoted Isomerization of Olefin Esters to Their alpha,beta-Unsaturated Esters: Methyl Oleate and Other Examples.

J. Org. Chem. 61(22) , 7784-7792, (1996)

Ultraviolet photolysis of stoichiometric amounts of methyl oleate and Fe(CO)(5) in hexanes solvent at 0 degrees C gives Fe(CO)(3)(eta(4)-alpha,beta-ester) in which the alpha,beta-unsaturated ester iso...

Synthesis of the pro-gly dipeptide alkene isostere using olefin cross-metathesis.

J. Org. Chem. 67(17) , 6240-2, (2002)

An approach to the synthesis of dipeptide olefin isosteres using intermolecular olefin cross-metathesis is presented. In particular, a synthesis of the Pro-Gly isostere (1) is reported. Conversion of ...

The flash vacuum thermolysis of (-)-cocaine. Sisti NJ, et al.

Tetrahedron Lett. 30(44) , 5977-80, (1989)

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