tris(2,2,2-trifluoroethyl)phosphite

Names

[ CAS No. ]:
370-69-4

[ Name ]:
tris(2,2,2-trifluoroethyl)phosphite

[Synonym ]:
Tris(2,2,2-trifluoroethyl) phosphite
tris(2,2,2-trifluoroethyl)phosphite
2,2,2-trifluoroethyl phosphite
tris(2,2,2-trifluoroethyl)phosphine
MFCD00009902
tris-(2,2,2-trifluoroethyl)phosphite
tri-(2,2,2-trifluoroethyl)phosphite
phosphoric acid tris-(2,2,2-trifluoro-ethyl ester)

Chemical & Physical Properties

[ Density]:
1.487

[ Boiling Point ]:
128.8±40.0 °C at 760 mmHg

[ Molecular Formula ]:
C₆H₆F₉O₃P

[ Molecular Weight ]:
328.069

[ Flash Point ]:
31.7±27.3 °C

[ Exact Mass ]:
327.991089

[ PSA ]:
41.28000

[ LogP ]:
2.98

[ Vapour Pressure ]:
12.7±0.2 mmHg at 25°C

[ Index of Refraction ]:
1.324

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S37/39

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2920901900

Synthetic Route

Click to get detail synthetic route

Customs

[ HS Code ]: 2920901900

[ Summary ]:
2920901900 VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

Articles

A new bis(2,2,2-trifluoroethyl)phosphonate for the synthesis of Z-unsaturated N-methoxy-N-methylamides.

J. Org. Chem. 67(15) , 5437-9, (2002)

The N-methoxy-N-methyl bis(2,2,2-trifluoroethyl)phosphonamide was easily obtained via the Arbuzov reaction with use of commercially available tris(2,2,2-trifluoroethyl)phosphite, 2-bromo-N-methoxy-N-m...

Towards a safe lithium-sulfur battery with a flame-inhibiting electrolyte and a sulfur-based composite cathode.

Angew. Chem. Int. Ed. Engl. 53(38) , 10099-104, (2014)

Of the various beyond-lithium-ion batteries, lithium-sulfur (Li-S) batteries were recently reported as possibly being the closest to market. However, its theoretically high energy density makes it pot...