chloro(4-fluorophenyl)sulfone

Names

[ CAS No. ]:
349-88-2

[ Name ]:
chloro(4-fluorophenyl)sulfone

[Synonym ]:
Benzenesulfonyl chloride,4-fluoro
Benzenesulfonyl chloride,p-fluoro
4-fluorobenzensulfonyl chloride
EINECS 206-493-0
4-FLUOROPHENYLSULFONYL CHLORIDE
P-FLUOROBENZENESULPHONYL CHLORIDE
4-Fluoro-benzenesulfonyl chloride
4-Fluorobenzenesulfonyl chloride
4-Fluorobenzene-1-Sulfonyl Chloride
4-fluorobenzene-sulfonyl chloride
Benzenesulfonyl chloride, p-fluoro-
MFCD00007438
chloro(4-fluorophenyl)sulfone
4-Fluorobenzenesulphonyl chloride
p-fluorophenylsulfonyl chloride
Benzenesulfonyl chloride, 4-fluoro-
p-Fluorobenzenesulfonyl chloride

Chemical & Physical Properties

[ Density]:
1.5±0.1 g/cm3

[ Boiling Point ]:
263.2±13.0 °C at 760 mmHg

[ Melting Point ]:
29-31 °C(lit.)

[ Molecular Formula ]:
C₆H₄ClFO₂S

[ Molecular Weight ]:
194.611

[ Flash Point ]:
113.0±19.8 °C

[ Exact Mass ]:
193.960449

[ PSA ]:
42.52000

[ LogP ]:
2.30

[ Vapour Pressure ]:
0.0±0.5 mmHg at 25°C

[ Index of Refraction ]:
1.534

[ Storage condition ]:
2~8℃

[ Water Solubility ]:
dioxane: 0.1 g/mL, clear

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS05

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H314

[ Precautionary Statements ]:
P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges

[ Hazard Codes ]:
C:Corrosive;

[ Risk Phrases ]:
R34

[ Safety Phrases ]:
S26-S28-S36/37/39-S45-S28A

[ RIDADR ]:
UN 3261 8/PG 2

[ WGK Germany ]:
3

[ Packaging Group ]:
II

[ Hazard Class ]:
8

[ HS Code ]:
2904909090

Precursor & DownStream

Precursor

DownStream

Customs

[ HS Code ]: 2904909090

[ Summary ]:
HS:2904909090 sulphonated, nitrated or nitrosated derivatives of hydrocarbons, whether or not halogenated VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

Articles

Application of the dissociative electron transfer theory and its extension to the case of in-cage interactions in the electrochemical reduction of arene sulfonyl chlorides.

Phys. Chem. Chem. Phys. 14(1) , 113-24, (2012)

Important aspects of the electrochemical reduction of a series of substituted arene sulfonyl chlorides are investigated. An interesting autocatalytic mechanism is encountered where the starting materi...

Peptide surface modification of P(HEMA-co-MMA)-b-PIB-b-P(HEMA-co-MMA) block copolymers.

Langmuir 25(11) , 6319-27, (2009)

Peptide surface modification of poly[(methyl methacrylate-co-hydroxyethyl methacrylate)-b-isobutylene-b-(methyl methacrylate-co-hydroxyethyl methacrylate)] P(MMA-co-HEMA)-b-PIB-b-P(MMA-co-HEMA) triblo...

Activating hydroxyl groups of polymeric carriers using 4-fluorobenzenesulfonyl chloride.

Bioconjug. Chem. 3(2) , 200-2, (1992)

4-Fluorobenzenesulfonyl chloride (fosyl chloride), due to the strong electron-withdrawing property of its fluoride atom, is found to be an excellent activating agent for the covalent attachment of bio...