Dibenzyl carbonate

Names

[ Name ]:
Dibenzyl carbonate

[Synonym ]:
Dibenzyl carbonate
Carbonic Acid Dibenzyl Ester
Benzyl carbonate
Carbonic acid,dibenzyl ester
Carbonic acid,bis(phenylmethyl) ester
S-benzyl carbonate
MFCD00014436
Carbonic acid, dibenzyl ester
phenylmethyl carbonate
EINECS 222-401-1
dibenzyl dicarbonate
PhCH2OCO2CH2Ph
Carbonic acid, bis(phenylmethyl) ester
phenylmethyl (phenylmethoxy)formate

Chemical & Physical Properties

[ Density]:
1.2±0.1 g/cm3

[ Boiling Point ]:
360.0±31.0 °C at 760 mmHg

[ Melting Point ]:
29-33 °C(lit.)

[ Molecular Formula ]:
C₁₅H₁₄O₃

[ Molecular Weight ]:
242.270

[ Flash Point ]:
138.4±13.9 °C

[ Exact Mass ]:
242.094299

[ PSA ]:
35.53000

[ LogP ]:
3.70

[ Vapour Pressure ]:
0.0±0.8 mmHg at 25°C

[ Index of Refraction ]:
1.568

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H302-H312

[ Precautionary Statements ]:
P280

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xn: Harmful;

[ Risk Phrases ]:
R21/22

[ Safety Phrases ]:
S36

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2920909090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

Customs

[ HS Code ]: 2920909090

[ Summary ]:
2920909090 esters of other inorganic acids of non-metals (excluding esters of hydrogen halides) and their salts; their halogenated, sulphonated, nitrated or nitrosated derivatives。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:6.5%。General tariff:30.0%

Articles

Selective mono-benzylation of methylene active compounds with dibenzyl carbonate: benzylation of phenol. AlbertoáMarques C.

J. Chem. Soc. Perkin Trans. I 15 , 1889-1893, (1995)

Synthesis of dibenzyl carbonate: towards a sustainable catalytic approach. Fiorani G and Selva M.

RSC Advances 4(4) , 1929-1937, (2014)

Selective N,N-dibenzylation of primary aliphatic amines with dibenzyl carbonate in the presence of phosphonium salts. Loris A, et al.

J. Org. Chem. 69(11) , 3953-3956, (2004)

Related Compounds

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