2-Bromothiazole

Names

[ Name ]:
2-Bromothiazole

[Synonym ]:
2-Bromothiazole
2-bromo-thiazole
2-Bromo-1,3-thiazole
bromothiazole
MFCD00005316
2-Bromo thiazole
EINECS 221-229-4
2-Thiazolyl Bromide
2-bromothioazole
Thiazole, 2-bromo-
Thiazole,2-bromo

Biological Activity

[Description]:

2-Bromothiazole is a biochemical reagent that can be used as a biological material or organic compound for life science related research.

[Related Catalog]:

Research Areas >> Others

[In Vitro]

2-溴噻唑，仅供研究使用。它也用作芳基卤化物，用于 N-芳基化 5-和 7-氮杂吲哚。铜催化氰化提供 2-氰基噻唑

Chemical & Physical Properties

[ Density]:
1.9±0.1 g/cm3

[ Boiling Point ]:
171.0±9.0 °C at 760 mmHg

[ Melting Point ]:
171ºC

[ Molecular Formula ]:
C₃H₂BrNS

[ Molecular Weight ]:
164.02

[ Flash Point ]:
63.3±0.0 °C

[ Exact Mass ]:
162.909119

[ PSA ]:
41.13000

[ LogP ]:
1.93

[ Vapour Pressure ]:
1.9±0.3 mmHg at 25°C

[ Index of Refraction ]:
1.605

[ Storage condition ]:
2-8°C

[ Water Solubility ]:
insoluble

MSDS

Click to get detail MSDS

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves;half-mask respirator (US);multi-purpose combination respirator cartridge (US)

[ Hazard Codes ]:
Xi: Irritant;F: Flammable;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S23-S24/25

[ RIDADR ]:
1993

[ WGK Germany ]:
3

[ HS Code ]:
29341000

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

Customs

[ HS Code ]: 2934100090

[ Summary ]:
2934100090 other compounds containing an unfused thiazole ring (whether or not hydrogenated) in the structure VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:20.0%

Articles

Synthesis and characterization of fused pyrrolo[3,2-d:4,5-d']bisthiazole-containing polymers.

Org. Lett. 12(23) , 5478-81, (2010)

The synthesis of a novel electron-deficient fused pyrrolo[3,2-d:4,5-d']bisthiazole is reported from 2-bromothiazole. This was copolymerized with thiophene, selenophene, thienothiophene, and bithiophen...

Regioselective functionalization of the thiazole scaffold using TMPMgCl·LiCl and TMP2Zn·2MgCl2·2LiCl.

J. Org. Chem. 76(16) , 6972-8, (2011)

A general method for the synthesis of 2,4,5-trisubstituted thiazoles has been developed. Starting from commercially available 2-bromothiazole, successive metalations using TMPMgCl·LiCl or TMP(2)Zn·2Mg...

Tetrahedron Lett. 48 , 4831, (2007)