2-((Benzyloxy)methyl)oxirane

Names

[ Name ]:
2-((Benzyloxy)methyl)oxirane

[Synonym ]:
2-[(Benzyloxy)methyl]oxirane
MFCD00068664
(+)-(Benzyloxymethyl)oxirane
Oxirane, [(phenylmethoxy)methyl]-
3-benzyloxypropyleneoxide
1-Benzyloxy-2,3-epoxypropane
(+)-Benzyl glycidyl ether
(R)-Benzyl glycidyl ether
(S)-Benzyl glycidyl ether
3-benzyloxy-1,2-epoxypropane
rac-benzyl glycidyl ether
2-((Benzyloxy)methyl)oxirane
rac-taxifolin
EINECS 220-899-5
Oxirane, 2-[(phenylmethoxy)methyl]-
2-(Benzyloxymethyl)oxirane
rac-1'-acetoxydihydrochavicol acetate
phenylmethoxymethyloxirane
rac-dihydrogalangal acetate
Dihydrogalangal acetate

Chemical & Physical Properties

[ Density]:
1.1±0.1 g/cm3

[ Boiling Point ]:
252.7±15.0 °C at 760 mmHg

[ Molecular Formula ]:
C₁₀H₁₂O₂

[ Molecular Weight ]:
164.201

[ Flash Point ]:
100.9±19.9 °C

[ Exact Mass ]:
164.083725

[ PSA ]:
21.76000

[ LogP ]:
2.04

[ Vapour Pressure ]:
0.0±0.5 mmHg at 25°C

[ Index of Refraction ]:
1.535

[ Storage condition ]:
Refrigerator

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :: TX2860000

CHEMICAL NAME :: Propane, 1-(benzyloxy)-2,3-epoxy-

CAS REGISTRY NUMBER :: 2930-05-4

BEILSTEIN REFERENCE NO. :: 0115279

LAST UPDATED :: 199612

DATA ITEMS CITED :: 1

MOLECULAR FORMULA :: C10-H12-O2

MOLECULAR WEIGHT :: 164.22

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

MUTATION DATA

TYPE OF TEST :: Mutation in microorganisms

TEST SYSTEM :: Bacteria - Salmonella typhimurium

DOSE/DURATION :: 6 mmol/L

REFERENCE :: CBINA8 Chemico-Biological Interactions. (Elsevier Scientific Pub. Ireland Ltd., POB 85, Limerick, Ireland) V.1- 1969- Volume(issue)/page/year: 45,153,1983

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S37-S39

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ RTECS ]:
TX2860000

[ HS Code ]:
2910900090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

Customs

[ HS Code ]: 2910900090

[ Summary ]:
2910900090. epoxides, epoxyalcohols, epoxyphenols and epoxyethers, with a three-membered ring, and their halogenated, sulphonated, nitrated or nitrosated derivatives. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0%

Articles

Synthesis of atactic and isotactic poly(1,2-glycerol carbonate)s: degradable polymers for biomedical and pharmaceutical applications.

J. Am. Chem. Soc. 135(18) , 6806-9, (2013)

The synthesis and characterization of atactic and isotactic linear poly(benzyl 1,2-glycerol carbonate)s are reported. The poly(benzyl 1,2-glycerol carbonate)s were obtained via the ring-opening copoly...

Biocatalytic resolution of benzyl glycidyl ether and its derivates by Talaromyces flavus: effect of phenyl ring substituents on enantioselectivity.

Biotechnol. Lett. 34(8) , 1499-503, (2012)

Talaromyces flavus containing a constitutive epoxide hydrolase (EH) resolved racemic benzyl glycidyl ether and nine derivatives into their (R)-enantiomers. After optimization of the fermentation condi...

Bioresolution of benzyl glycidyl ether using whole cells of Bacillus alcalophilus.

J. Basic Microbiol. 52(4) , 383-9, (2012)

The incubation of whole Bacillus alcalophilus cells grown on a mineral supplemented medium (MSM) containing 1% (w/v) sucrose as carbon source, 1.2% (w/v) tryptone as nitrogen source at pH 6.5 and temp...

Related Compounds

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