4-Amino-3-methylphenol
Names
[ CAS No. ]:
2835-99-6
[ Name ]:
4-Amino-3-methylphenol
[Synonym ]:
2-methyl-4-hydroxy aniline
4-Amino-3-methylphenol
4-hydroxy-2-methylphenylamine
4-Amino-m-cresol
p-amino-m-methylphenol
p-Hydroxy-o-toluidine
4-Hydroxy-2-methylaniline
4-hydroxy-6-methylaniline
3-Methyl-4-aminophenol
4-Amino-Meta-Cresol
p-Amino-m-cresol
Phenol,4-amino-3-methyl
2-methyl-1-amino-4-hydroxybenzene
Phenol, 4-amino-3-methyl-
MFCD00007871
2-Amino-5-hydroxytoluene
m-CRESOL,4-AMINO
EINECS 220-621-2
Chemical & Physical Properties
[ Density]:
1.2±0.1 g/cm3
[ Boiling Point ]:
286.7±28.0 °C at 760 mmHg
[ Melting Point ]:
176-179 °C(lit.)
[ Molecular Formula ]:
C7H9NO
[ Molecular Weight ]:
123.152
[ Flash Point ]:
127.2±24.0 °C
[ Exact Mass ]:
123.068413
[ PSA ]:
46.25000
[ LogP ]:
0.17
[ Vapour Pressure ]:
0.0±0.6 mmHg at 25°C
[ Index of Refraction ]:
1.616
[ Water Solubility ]:
insoluble
MSDS
Toxicological Information
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- GO6826000
- CHEMICAL NAME :
- m-Cresol, 4-amino-
- CAS REGISTRY NUMBER :
- 2835-99-6
- BEILSTEIN REFERENCE NO. :
- 2078803
- LAST UPDATED :
- 199701
- DATA ITEMS CITED :
- 2
- MOLECULAR FORMULA :
- C7-H9-N-O
- MOLECULAR WEIGHT :
- 123.17
- WISWESSER LINE NOTATION :
- ZR DQ B1
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Intraperitoneal
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 680 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- NNGADV Nippon Noyaku Gakkaishi. Journal of the Pesticide Science Society of Japan. (Nippon Noyaku Gakkai, 1-43-11, Komagome, Toshima-ku, Tokyo 170, Japan) V.1- 1976- Volume(issue)/page/year: 3,35,1978
Safety Information
[ Symbol ]:
GHS07
[ Signal Word ]:
Warning
[ Hazard Statements ]:
H302-H315-H319-H335
[ Precautionary Statements ]:
P261-P305 + P351 + P338
[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves
[ Hazard Codes ]:
Xn:Harmful
[ Risk Phrases ]:
R22;R36/37/38
[ Safety Phrases ]:
S26-S37/39-S36/37/39
[ RIDADR ]:
UN3077
[ WGK Germany ]:
3
[ RTECS ]:
GO6826000
[ Packaging Group ]:
III
[ Hazard Class ]:
9
[ HS Code ]:
29222900
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Customs
[ HS Code ]: 2922299090
[ Summary ]:
2922299090. other amino-naphthols and other amino-phenols, other than those containing more than one kind of oxygen function, their ethers and esters; salts thereof. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%
Articles
Arch. Biochem. Biophys. 372(1) , 97-106, (1999)
Mechanisms of DNA damage by metabolites of carcinogenic o-toluidine in the presence of metals were investigated by the DNA sequencing technique using (32)P-labeled human DNA fragments. 4-Amino-3-methy...
Biotransformation of 3-methyl-4-nitrophenol, a main product of the insecticide fenitrothion, by Aspergillus niger.J. Agric. Food Chem. 53(16) , 6426-31, (2005)
Biotransformation of the environmental pollutant 3-methyl-4-nitrophenol (MNP), a newly characterized estrogenic chemical, and the primary breakdown product of the heavily used insecticide fenitrothion...
Recognition of sequence-information in synthetic copolymer chains by a conformationally-constrained tweezer molecule.Faraday Discuss. 143 , 205-20; discussion 265-75, (2009)
A novel type of tweezer molecule containing electron-rich 2-pyrenyloxy arms has been designed to exploit intramolecular hydrogen bonding in stabilising a preferred conformation for supramolecular comp...