1,3-BIS(2,6-DIISOPROPYLPHENYL)-IMIDAZOLIDINIUM-CHLORIDE
Names
[ CAS No. ]:
258278-25-0
[ Name ]:
1,3-BIS(2,6-DIISOPROPYLPHENYL)-IMIDAZOLIDINIUM-CHLORIDE
[Synonym ]:
SIPr.HCl
MFCD07369796
1H-Imidazolium, 1,3-bis[2,6-bis(1-methylethyl)phenyl]-4,5-dihydro-, chloride (1:1)
1,3-Bis(2,6-diisopropylphenyl)iMidazoliniuM Chloride
1,3-Bis(2,6-diisopropylphenyl)-4,5-dihydro-1H-imidazol-3-ium chloride
1,3-Bis(2,6-diisopropylphenyl)imidazolidinium chloride
Chemical & Physical Properties
[ Melting Point ]:
289-293ºC(lit.)
[ Molecular Formula ]:
C27H39ClN2
[ Molecular Weight ]:
427.065
[ Exact Mass ]:
426.280182
[ PSA ]:
6.25000
[ LogP ]:
7.39650
MSDS
Safety Information
[ Symbol ]:
GHS07
[ Signal Word ]:
Warning
[ Hazard Statements ]:
H315-H319-H335
[ Precautionary Statements ]:
P261-P305 + P351 + P338
[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves
[ Hazard Codes ]:
Xi: Irritant;
[ Risk Phrases ]:
R36/37/38
[ Safety Phrases ]:
S26
[ RIDADR ]:
NONH for all modes of transport
Articles
Angew. Chem. Int. Ed. Engl. 44 , 2026, (2005)
NHC-catalyzed ring expansion of oxacycloalkane-2-carboxaldehydes: a versatile synthesis of lactones.
Org. Lett. 11 , 891, (2009)
Imidazolinium-derived carbenes catalyze the ring-expansion lactonization of oxacycloalkane-2-carboxaldehydes. A variety of functionalized five-, six-, and seven-membered lactones can be formed efficie...
Palladium-imidazolium carbene catalyzed Mizoroki-Heck coupling with aryl diazonium ions.J. Org. Chem. 4 , 2079, (2002)
[reaction: see text] Catalyst formed from N,N-bis(2,6-diisopropylphenyl)dihydroimidazolium chloride and palladium(II) acetate (2 mol %) was used, without added base, to efficiently produce Heck couple...