2-CHLORO-5 5-DIMETHYL-1 3 2-DIOXAPHOSPHO

Names

[ Name ]:
2-CHLORO-5 5-DIMETHYL-1 3 2-DIOXAPHOSPHO

[Synonym ]:
neopentylene phosphorochloridite
5,5-dimethyl-2-chloro-1,3,2-dioxaphosphorinane
1-chloro-4,4-dimethyl-1-phospha-2,6-dioxahexane
2-Chloro-5,5-dimethyl-1,3,2-dioxaphosphorinane,AcroSeal
EINECS 219-380-6
MFCD03093988
2-Chloro-5,5-dimethyl-1,3,2-dioxaphosphorinane

Chemical & Physical Properties

[ Boiling Point ]:
164.8ºC at 760mmHg

[ Molecular Formula ]:
C₄H₈ClO₂P

[ Molecular Weight ]:
154.53200

[ Flash Point ]:
53.5ºC

[ Exact Mass ]:
153.99500

[ PSA ]:
32.05000

[ LogP ]:
2.27750

[ Vapour Pressure ]:
2.54mmHg at 25°C

[ Index of Refraction ]:
n20/D 1.476(lit.)

Safety Information

[ Symbol ]:

GHS05

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H314

[ Supplemental HS ]:
Reacts violently with water.

[ Precautionary Statements ]:
P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
C: Corrosive;

[ Risk Phrases ]:
14-34

[ Safety Phrases ]:
26-36/37/39-45

[ RIDADR ]:
UN 3094 8/PG 2

[ HS Code ]:
2934999090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

Customs

[ HS Code ]: 2934999090

[ Summary ]:
2934999090. other heterocyclic compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

Articles

An improved synthesis of benzyl 3, 5-di-O-benzyl-2-deoxy-1, 4-dithio-d-erythro-pentofuranoside, an intermediate in the synthesis of 4'-thionucleosides. Dyson MR, et al.

Carbohydr. Res. 216 , 237-248, (1992)

Bis(µ-5, 5-dimethyl-1, 3, 2-dioxaphosphorinano)-diiron hexacarbonyl: a fluxional molecule exhibiting two types of proton site exchange. Bartish, Charles M., and Charles S. Kraihanzel.

Inorganic Chemistry 17(3) , 735-738, (1978)

Tungsten (Z)-1, 2-diphosphite-alkene and (E)-vinyl-phosphite complexes from phosphite Fischer carbene complexes. Barluenga J, et al.

Organometallics 16(17) , 3732-3734, (1997)