1-methoxycyclohexa-1,3-diene

[ Density]:
0.93g/cm3

[ Boiling Point ]:
143.8ºC at 760mmHg

[ Molecular Formula ]:
C₇H₁₀O

[ Molecular Weight ]:
110.15400

[ Flash Point ]:
51.1ºC

[ Exact Mass ]:
110.07300

[ PSA ]:
9.23000

[ LogP ]:
1.86670

[ Vapour Pressure ]:
6.61mmHg at 25°C

[ Index of Refraction ]:
n20/D 1.488(lit.)

Click to get detail MSDS

[ Symbol ]:

GHS02, GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H226-H302 + H312 + H332

[ Precautionary Statements ]:
P280

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xn: Harmful;

[ Risk Phrases ]:
10-20/21/22

[ Safety Phrases ]:
16-33-36/37/39

[ RIDADR ]:
UN 1993 3/PG 3

[ Packaging Group ]:
III

[ Hazard Class ]:
3.2

[ HS Code ]:
2909209000

Click to get detail synthetic route

Precursor

DownStream

[ HS Code ]: 2909209000

[ Summary ]:
2909209000 other cyclanic, cyclenic or cyclotherpenic ethers and their halogenated, sulphonated, nitrated or nitrosated derivatives。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:5.5%。General tariff:30.0%

Remote Regiocontrol by a Thioether Group in Diels-Alder Reactions of Naphthazarin: Regioselective Access to Tetracyclic Polyhydroxyquinones.

J. Org. Chem. 61(18) , 6136-6138, (1996)

The synthesis of tetracyclic polyhydroxyquinones 5a and 5b was achieved through a sequence involving two Diels-Alder reactions with 1-methoxy-1,3-cyclohexadiene: the first with 2-(p-tolylthio)naphthaz...

Synthesis of tetra-ortho-substituted, phosphorus-containing and carbonyl-containing biaryls utilizing a Diels-Alder approach.

J. Am. Chem. Soc. 129(29) , 9109-16, (2007)

The application of the Diels-Alder approach to biaryls (DAB) is described for the synthesis of tetra-ortho-substituted biaryl compounds containing orthogonally functionalized substituents. The synthes...

Diels-Alder approach to biaryls (DAB): importance of the ortho-nitro moiety in the [4 + 2] cycloaddition.

Org. Biomol. Chem. 6(2) , 255-7, (2008)

A series of nitrophenyl acetylenes were evaluated for their utility in a cycloaddition-cycloreversion approach to polysubstituted biaryls. ortho-Nitrophenyl acetylene consistently provided the target ...

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