Dichloro[9,9-dimethyl-4,5-bis(diphenylphosphino)xanthene]palladium(II)
Names
[ CAS No. ]:
205319-10-4
[ Name ]:
Dichloro[9,9-dimethyl-4,5-bis(diphenylphosphino)xanthene]palladium(II)
[Synonym ]:
Palladium(2+) chloride - (9,9-dimethyl-9H-xanthene-4,5-diyl)bis(diphenylphosphine) (1:2:1)
[4,5-Bis(diphenylphosphino)-9,9-dimethylxanthene]dichloropalladium(II)
Phosphine, 1,1'-(9,9-dimethyl-9H-xanthene-4,5-diyl)bis[1,1-diphenyl-, palladium(2+) salt, hydrochloride (1:1:2)
[4,5-Bis(diphenylphosphino)-9,9-dimethylxanthene]palladium(II) Dichloride
Dichloro[9,9-dimethyl-4,5-bis(diphenylphosphino)xanthene]palladium(II)
Biological Activity
[Description]:
[Related Catalog]:
Chemical & Physical Properties
[ Melting Point ]:
287 °C(dec.)
[ Molecular Formula ]:
C39H32Cl2OP2Pd
[ Molecular Weight ]:
755.94
[ Exact Mass ]:
754.033997
[ PSA ]:
36.41000
[ LogP ]:
1.64260
MSDS
Safety Information
[ RIDADR ]:
NONH for all modes of transport
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Articles
Chem. Commun. (Camb.) 48 , 8012, (2012)
Aryl formates are efficient carbon monoxide sources in palladium-catalyzed esterification of aryl halides. The carbonylation readily proceeds at ambient pressure without the use of external carbon mon...
Palladium-catalyzed oxidative carbonylation of benzylic C-H bonds via nondirected C(sp3)-H activation.J. Am. Chem. Soc. 134 , 9902, (2012)
A new strategy for generating benzylpalladium reactive species from toluenes via nondirected C(sp(3))-H activation has been developed. This led to construction of an efficient Pd-catalyzed reaction pr...
Improved carbonylation of heterocyclic chlorides and electronically challenging aryl bromides.Org. Lett. 6 , 2097, (2004)
[reaction: see text] Optimized conditions are described that effect the carbonylation of diverse heterocyclic chlorides to yield the desired alkyl esters. In addition, bromoanilines and bromoanisoles,...