Diisopropylcarbamic chloride

[ Density]:
1.0±0.1 g/cm3

[ Boiling Point ]:
204.3±0.0 °C at 760 mmHg

[ Melting Point ]:
57-59ºC(lit.)

[ Molecular Formula ]:
C₇H₁₄ClNO

[ Molecular Weight ]:
163.645

[ Flash Point ]:
82.4±18.7 °C

[ Exact Mass ]:
163.076385

[ PSA ]:
20.31000

[ LogP ]:
2.00

[ Appearance of Characters ]:
Crystalline Powder or To Low Melting Solid | Colorless to pale yellow or white to pale yellow

[ Vapour Pressure ]:
0.3±0.4 mmHg at 25°C

[ Index of Refraction ]:
1.448

Click to get detail MSDS

[ Symbol ]:

GHS05

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H314

[ Precautionary Statements ]:
P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges

[ Hazard Codes ]:
C

[ Risk Phrases ]:
34

[ Safety Phrases ]:
26-36/37/39-45

[ RIDADR ]:
UN 3261 8/PG 2

[ WGK Germany ]:
3

[ Packaging Group ]:
III

[ HS Code ]:
2903199000

Click to get detail synthetic route

Precursor

DownStream

[ HS Code ]: 2903199000

[ Summary ]:
2903199000 other saturated chlorinated derivatives of acyclic hydrocarbons。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:5.5%。General tariff:30.0%

Stereoselective Intermolecular Carbolithiation of Open-Chain and Cyclic 1-Aryl-1-alkenyl N,N-Diisopropylcarbamates Coupled with Electrophilic Substitution. Observation of p-Carboxylation in a Benzyllithium Derivative. Peters JG, et al.

Synthesis 03 , 0381-292, (2002)

Asymmetric ?-Deprotonation and Substitution Reactions of (Z)-1, 3-Diphenyl-1-propenyl N, N-Diisopropylcarbamate. Reuber J, et al.

European J. Org. Chem. 14 , 3017-25, (2005)

The total synthesis of (-)-aplysin via a lithiation-borylation-propenylation sequence. Fletcher CJ, et al.

Tetrahedron 68(23) , 7598-7604, (2012)

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