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phenyl trifluoromethanesulfonate

Names

[ CAS No. ]:
17763-67-6

[ Name ]:
phenyl trifluoromethanesulfonate

[Synonym ]:
trifluoromethanesulfonyloxybenzene
phenyl triflate
MFCD00192399
Trifluoromethanesulfonic Acid Phenyl Ester
Phenyl TrifluoroMethanesulfonate
phenol triflate

Chemical & Physical Properties

[ Density]:
1.396 g/mL at 25ºC(lit.)

[ Boiling Point ]:
99-100ºC60 mm Hg(lit.)

[ Molecular Formula ]:
C7H5F3O3S

[ Molecular Weight ]:
226.17300

[ Flash Point ]:
160 °F

[ Exact Mass ]:
225.99100

[ PSA ]:
51.75000

[ LogP ]:
2.99580

[ Vapour Pressure ]:
0.0862mmHg at 25°C

[ Index of Refraction ]:
n20/D 1.435(lit.)

MSDS

Safety Information

[ Symbol ]:

GHS05, GHS06

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H301-H311-H314

[ Precautionary Statements ]:
P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
T: Toxic;

[ Risk Phrases ]:
36/37/38-34-24/25

[ Safety Phrases ]:
26-36-45-36/37/39

[ RIDADR ]:
UN 2927 6.1/PG 2

[ WGK Germany ]:
3

Synthetic Route

Precursor & DownStream

Articles

Enantioselective alpha-arylation of ketones with aryl triflates catalyzed by difluorphos complexes of palladium and nickel.

J. Am. Chem. Soc. 130(1) , 195-200, (2008)

The asymmetric alpha-arylation of ketones with aryl triflates is described, and the use of this electrophile with nickel and palladium catalysts containing a segphos derivative increases substantially...

One-pot synthesis of carbazoles by palladium-catalyzed N-arylation and oxidative coupling. Watanabe T, et al.

Chem. Commun. (Camb.) 43 , 4516-4518, (2007)

Regioselective arylation of benzanilides with aryl triflates or bromides under palladium catalysis. Kametani Y, et al.

Tetrahedron Lett. 41(15) , 2655-2658, (2000)


More Articles


Related Compounds

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