2-Methyl-indanone

Names

[ Name ]:
2-Methyl-indanone

[Synonym ]:
2-Methylindan-1-One
2-methyl-2,3-dihydroinden-1-one
1H-Inden-1-one, 2,3-dihydro-2-methyl-
2-Methyl-indanone
2-methyl-2,3-dihydro-1H-inden-1-one
2-Methyl-1-indanone
MFCD00192303

Chemical & Physical Properties

[ Density]:
1.1±0.1 g/cm3

[ Boiling Point ]:
238.4±10.0 °C at 760 mmHg

[ Molecular Formula ]:
C₁₀H₁₀O

[ Molecular Weight ]:
146.186

[ Flash Point ]:
94.4±14.0 °C

[ Exact Mass ]:
146.073166

[ PSA ]:
17.07000

[ LogP ]:
2.59

[ Vapour Pressure ]:
0.0±0.5 mmHg at 25°C

[ Index of Refraction ]:
1.554

MSDS

Click to get detail MSDS

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves

[ Hazard Codes ]:
Xi: Irritant;Xn: Harmful;

[ Risk Phrases ]:
R22

[ Safety Phrases ]:
23-26-36/37/39-36

[ RIDADR ]:
NONH for all modes of transport

[ HS Code ]:
2914399090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

Customs

[ HS Code ]: 2914399090

[ Summary ]:
2914399090. other aromatic ketones without other oxygen function. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0%

Articles

The O-acylation of ketone enolates by allyl 1H-imidazole-1-carboxylate mediated with boron trifluoride etherate: a convenient procedure for the synthesis of substituted allyl enol carbonates.

J. Org. Chem. 72(24) , 9372-5, (2007)

A convenient access to substituted allyl enol carbonates was established through the reaction of ketone enolates with the complex of allyl 1H-imidazole-1-carboxylates and boron trifluoride etherate.

Recent advances in enzymatic and chemical deracemisation of racemic compounds.

Chem. Soc. Rev. 42(24) , 9268-9282, (2013)

Deracemisation of racemic compounds is still the most important strategy to produce optically pure compounds despite many recent advances in asymmetric synthesis. Especially deracemisation approaches ...

Amino alcohol-mediated enantioselective syntheses of α-substituted indanones and tetralones, ammonium enolates as key intermediates. Muzart J.

Tetrahedron Asymmetry 25(9) , 697-704, (2014)