8-Bromoquinoline

[ Density]:
1.6±0.1 g/cm3

[ Boiling Point ]:
303.0±0.0 °C at 760 mmHg

[ Melting Point ]:
58-59 °C

[ Molecular Formula ]:
C₉H₆BrN

[ Molecular Weight ]:
208.055

[ Flash Point ]:
132.8±19.8 °C

[ Exact Mass ]:
206.968353

[ PSA ]:
12.89000

[ LogP ]:
2.51

[ Vapour Pressure ]:
0.0±0.6 mmHg at 25°C

[ Index of Refraction ]:
1.674

[ Storage condition ]:
Refrigerator (+4°C)

Click to get detail MSDS

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi:Irritant

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36-S37/39

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2933499090

Click to get detail synthetic route

Precursor

DownStream

[ HS Code ]: 2933499090

[ Summary ]:
2933499090. other compounds containing in the structure a quinoline or isoquinoline ring-system (whether or not hydrogenated), not further fused. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

Reactivity of the bifunctional ambiphilic molecule 8-(dimesitylboryl)quinoline: hydrolysis and coordination to Cu(I), Ag(I) and Pd(II).

Dalton Trans. 39(45) , 11081-90, (2010)

The ambiphilic molecule 8-(dimesitylboryl)quinoline (1) was synthesized by treatment of 8-bromoquinoline or 8-iodoquinoline with n-BuLi followed by dimesitylboronfluoride. Hydrolysis of 1 is unusually...

Direct synthesis of tricyclic 5H-pyrido[3,2,1-ij]quinolin-3-one by domino palladium catalyzed reaction.

Org. Biomol. Chem. 4(20) , 3760-2, (2006)

Unexpectedly, the palladium catalyzed coupling reaction of acrolein with 8-bromoquinoline gave 5H-pyrido[3,2,1-ij]quinolin-3-one in a single step.

Facile synthesis of 8-substituted quinolines. Suggs JW and Pearson GDN.

J. Org. Chem. 45(8) , 1514-15, (1980)

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