Ethyl oxophenylacetate

Names

[ Name ]:
Ethyl oxophenylacetate

[Synonym ]:
ethyl 2-oxo-2-phenylacetate
Ethyl phenylglyoxylate
Ethyl oxophenylacetate
Glyoxylic acid, phenyl-, ethyl ester (8CI)
Ethyloxo(phenyl)acetat
Benzoylformic Acid Ethyl Ester
Phenylglyoxylic Acid Ethyl Ester
Ethyl oxo(phenyl)acetate
ethyl phenyloxoacetate
Glyoxylic acid, phenyl-, ethyl ester
MFCD00009120
ETHYL α-OXOBENZENEACETATE
EINECS 216-504-0
Benzeneacetic acid, α-oxo-, ethyl ester
Ethyl benzoylformate

Biological Activity

[Description]:

Ethyl phenylglyoxylate (Ethyl benzoylformate; Phenylglyoxylic acid ethyl ester) is the ethyl ester of phenylglyoxylic acid, used as a synthetic reagent[1].

[Related Catalog]:

Research Areas >> Others

Signaling Pathways >> Others >> Others

[References]

[1]. Shengkui Hu, et al. Photochemically Active Polymers Containing Pendant Ethyl Phenylglyoxylate. Macromolecules 1998, 31, 2, 322–327.

Chemical & Physical Properties

[ Density]:
1.1±0.1 g/cm3

[ Boiling Point ]:
256.5±0.0 °C at 760 mmHg

[ Melting Point ]:
97ºC

[ Molecular Formula ]:
C₁₀H₁₀O₃

[ Molecular Weight ]:
178.185

[ Flash Point ]:
111.4±15.9 °C

[ Exact Mass ]:
178.062988

[ PSA ]:
43.37000

[ LogP ]:
1.80

[ Vapour Pressure ]:
0.0±0.5 mmHg at 25°C

[ Index of Refraction ]:
1.513

MSDS

Click to get detail MSDS

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves

[ Hazard Codes ]:
Xi: Irritant;

[ Safety Phrases ]:
S24/25

[ RIDADR ]:
NONH for all modes of transport

[ HS Code ]:
2942000000

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

Customs

[ HS Code ]: 2918300090

[ Summary ]:
2918300090 other carboxylic acids with aldehyde or ketone function but without other oxygen function, their anhydrides, halides, peroxides, peroxyacids and their derivatives。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:6.5%。General tariff:30.0%

Articles

98% Enantioselectivity in the asymmetric synthesis of a useful chiral building block by heterogeneous method: Enantioselective hydrogenation of ethyl-benzoylformate over cinchona modified Pt/Al₂ O₃ catalysts in the acetic acid. Sutyinszki M, et al.

Catal. Commun. 3(3) , 125-7, (2002)

Preparation of chiral 5-deazaflavin derivatives and their asymmetric reduction of ethyl benzoylformate. Tanaka K, et al.

Tetrahedron Lett. 25(16) , 1741-2, (1984)

Related Compounds

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