Dirhodium tetraacetate

Names

[ Name ]:
Dirhodium tetraacetate

[Synonym ]:
Rhodium(II) acetate dimer dihydrate
Rhodium(II) acetate dimer
Dirhodium(II) Tetraacetate
Acetic acid, rhodium(2+) salt (2:1)
EINECS 240-084-8
MFCD00003538
dirhodium tetraacetate
Tetrakis(acetato)dirhodium(II)
Dirhodium tetraacetate (Tetrakis(acetato)dirhodium(II)
Rhodium(2+) acetate (1:2)
Rhodium(II)acetatedimer

Biological Activity

[Description]:

Dirhodium tetraacetate is a biochemical reagent that can be used as a biological material or organic compound for life science related research.

[Related Catalog]:

Research Areas >> Others

Signaling Pathways >> Others >> Others

Chemical & Physical Properties

[ Boiling Point ]:
117.1ºC at 760 mmHg

[ Melting Point ]:
205ºC

[ Molecular Formula ]:
C₈H₁₂O₈Rh₂

[ Molecular Weight ]:
441.99

[ Flash Point ]:
40ºC

[ Exact Mass ]:
441.864227

[ PSA ]:
105.20000

[ LogP ]:
0.05520

[ Vapour Pressure ]:
13.9mmHg at 25°C

[ Storage condition ]:
Store below +30°C.

[ Water Solubility ]:
Soluble in aqueous solution like water. Slightly soluble in ethanol

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :: VI9361000

CHEMICAL NAME :: Rhodium, tetrakis(mu-acetato)di-

CAS REGISTRY NUMBER :: 15956-28-2

LAST UPDATED :: 198909

DATA ITEMS CITED :: 1

MOLECULAR FORMULA :: C8-H12-O8-Rh2

MOLECULAR WEIGHT :: 442.02

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD10 - Lethal Dose

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 115 mg/kg

TOXIC EFFECTS :: Tumorigenic - active as anti-cancer agent

REFERENCE :: JMCMAR Journal of Medicinal Chemistry. (American Chemical Soc., Distribution Office Dept. 223, POB POB 57136, West End Stn., Washington, DC 20037) V.6- 1963- Volume(issue)/page/year: 20,943,1977

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ Hazard Codes ]:
Xi: Irritant;

[ Risk Phrases ]:
R36/38

[ Safety Phrases ]:
S15-S26-S37/39

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ RTECS ]:
VI9361000

[ HS Code ]:
2942000000

Synthetic Route

Click to get detail synthetic route

Customs

[ HS Code ]: 2942000000

Articles

Rhodium acetate/base-catalyzed N-silylation of indole derivatives with hydrosilanes.

Chem. Commun. (Camb.) 48(74) , 9269-71, (2012)

In the presence of Rh(2)(OAc)(4) (OAc = acetate) and TBA(2)WO(4) (TBA = tetra-n-butylammonium), the N-silylation of indole derivatives with hydrosilanes efficiently proceeded to give the corresponding...

One-pot protocol to functionalized benzopyrrolizidine catalyzed successively by Rh2(OAc)4 and Cu(OTf)2: a transition metal-Lewis acid catalysis relay.

Org. Lett. 17(1) , 66-9, (2015)

4-N-allylarylpropylamino-1-sulfonyl triazoles are converted to structurally unique benzopyrrolizidinyl sulfonamides in a one-pot operation. Intramolecular capture of rhodium carbene with arylamino nit...

Unprecedented head-to-head conformers of d(GpG) bound to the antitumor active compound tetrakis (mu-carboxylato)dirhodium(II,II).

J. Am. Chem. Soc. 125(35) , 10703-13, (2003)

The N7/O6 equatorial binding interactions of the antitumor active complex Rh(2)(OAc)(4)(H(2)O)(2) (OAc(-) = CH(3)CO(2)(-)) with the DNA fragment d(GpG) have been unambiguously determined by NMR spectr...