4-(Trifluoromethyl)phenyl isocyanate

Names

[ Name ]:
4-(Trifluoromethyl)phenyl isocyanate

[Synonym ]:
Isocyanic Acid 4-(Trifluoromethyl)phenyl Ester
α,α,α-Trifluoro-p-tolyl isocyanate
1-Isocyanato-4-(trifluoromethyl)benzene
EINECS 216-284-6
alpha,alpha,alpha-Trifluoro-p-tolyl isocyanate
MFCD00002028
Benzene, 1-isocyanato-4-(trifluoromethyl)-
4-(Trifluoromethyl)phenyl isocyanate

Chemical & Physical Properties

[ Density]:
1.3±0.1 g/cm3

[ Boiling Point ]:
172.5±0.0 °C at 760 mmHg

[ Molecular Formula ]:
C₈H₄F₃NO

[ Molecular Weight ]:
187.119

[ Flash Point ]:
70.0±0.0 °C

[ Exact Mass ]:
187.024506

[ PSA ]:
29.43000

[ LogP ]:
3.55

[ Vapour Pressure ]:
1.3±0.3 mmHg at 25°C

[ Index of Refraction ]:
1.462

[ Storage condition ]:
2-8°C

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07, GHS08

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H302 + H312 + H332-H315-H319-H334-H335

[ Precautionary Statements ]:
P261-P280-P305 + P351 + P338-P342 + P311

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xn: Harmful;T: Toxic;

[ Risk Phrases ]:
R20/21/22

[ Safety Phrases ]:
S26-S36/37/39

[ RIDADR ]:
UN 3382 6.1/PG 1

[ WGK Germany ]:
3

[ Packaging Group ]:
II

[ Hazard Class ]:
6.1

[ HS Code ]:
2929109000

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

Customs

[ HS Code ]: 2929109000

[ Summary ]:
2929109000. other isocyanates. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

Articles

Synthesis and photophysical evaluation of charge neutral thiourea or urea based fluorescent PET sensors for bis-carboxylates and pyrophosphate.

Org. Biomol. Chem. 3(1) , 48-56, (2005)

The synthesis of the fluorescent photoinduced electron transfer (PET) chemosensors 1-3 for bis-anions such as bis-carboxylates and pyrophosphate in organic solvents is described herein. These sensors ...

Colorimetric 'naked-eye'and fluorescent sensors for anions based on amidourea functionalised 1, 8-naphthalimide structures: anion recognition via either deprotonation or hydrogen bonding in DMSO. Ali HDP, et al.

New J. Chem. 32(7) , 1153-61, (2008)

3-Urea-1, 8-naphthalimides are good chemosensors: a highly selective dual colorimetric and fluorescent ICT based anion sensor for fluoride. Duke RM and Gunnlaugsson T.

Tetrahedron Lett. 52(13) , 1503-5, (2011)