Benzene,2-nitro-1-(4-nitrophenoxy)-4-(trifluoromethyl)-
Names
[ CAS No. ]:
15457-05-3
[ Name ]:
Benzene,2-nitro-1-(4-nitrophenoxy)-4-(trifluoromethyl)-
[Synonym ]:
2-nitro-1-(4-nitrophenoxy)-4-(trifluoromethyl)benzene
4-nitrophenyl α,α,α-trifluoro-2-nitro-p-tolyl ether
MFCD00055532
EINECS 239-474-0
Flurodifen
Chemical & Physical Properties
[ Density]:
1.51g/cm3
[ Boiling Point ]:
371.1ºC at 760 mmHg
[ Melting Point ]:
94℃
[ Molecular Formula ]:
C13H7F3N2O5
[ Molecular Weight ]:
328.20000
[ Flash Point ]:
178.2ºC
[ Exact Mass ]:
328.03100
[ PSA ]:
100.87000
[ LogP ]:
5.36050
[ Vapour Pressure ]:
2.26E-05mmHg at 25°C
[ Index of Refraction ]:
1.565
MSDS
Toxicological Information
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- KO2750000
- CHEMICAL NAME :
- Ether, (p-nitrophenyl) (alpha,alpha,alpha-trifluoro-2-nitro-p-tolyl)
- CAS REGISTRY NUMBER :
- 15457-05-3
- LAST UPDATED :
- 199701
- DATA ITEMS CITED :
- 8
- MOLECULAR FORMULA :
- C13-H7-F3-N2-O5
- MOLECULAR WEIGHT :
- 328.22
- WISWESSER LINE NOTATION :
- WNR DOR BNW BXFFF
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
- TYPE OF TEST :
- Standard Draize test
- ROUTE OF EXPOSURE :
- Administration into the eye
- SPECIES OBSERVED :
- Rodent - rabbit
- REFERENCE :
- CIGET* Ciba-Geigy Toxicology Data/Indexes. (Ciba-Geigy Corp., 556 Morris Ave., Summit, NJ 07901) Volume(issue)/page/year: -,-,1977 ** ACUTE TOXICITY DATA **
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 9 gm/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- PEMNDP Pesticide Manual. (The British Crop Protection Council, 20 Bridport Rd., Thornton Heath CR4 7QG, UK) V.1- 1968- Volume(issue)/page/year: 8,414,1987
- TYPE OF TEST :
- LC50 - Lethal concentration, 50 percent kill
- ROUTE OF EXPOSURE :
- Inhalation
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- >990 mg/m3/6H
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- PEMNDP Pesticide Manual. (The British Crop Protection Council, 20 Bridport Rd., Thornton Heath CR4 7QG, UK) V.1- 1968- Volume(issue)/page/year: 8,414,1987
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Administration onto the skin
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- >3 gm/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- PEMNDP Pesticide Manual. (The British Crop Protection Council, 20 Bridport Rd., Thornton Heath CR4 7QG, UK) V.1- 1968- Volume(issue)/page/year: 8,414,1987
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- >15 gm/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- CIGET* Ciba-Geigy Toxicology Data/Indexes. (Ciba-Geigy Corp., 556 Morris Ave., Summit, NJ 07901) Volume(issue)/page/year: -,-,1972
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Administration onto the skin
- SPECIES OBSERVED :
- Rodent - rabbit
- DOSE/DURATION :
- >10 gm/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- CIGET* Ciba-Geigy Toxicology Data/Indexes. (Ciba-Geigy Corp., 556 Morris Ave., Summit, NJ 07901) Volume(issue)/page/year: -,-,1972
Safety Information
[ Symbol ]:
GHS07, GHS09
[ Signal Word ]:
Warning
[ Hazard Statements ]:
H319-H332-H400
[ Precautionary Statements ]:
P273-P305 + P351 + P338
[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Faceshields;Gloves
[ Hazard Codes ]:
Xi,N
[ Risk Phrases ]:
R36;R50/53
[ Safety Phrases ]:
S26;S60;S61
[ RIDADR ]:
UN3077 9/PG 3
[ RTECS ]:
KO2750000
[ HS Code ]:
2909309014
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Customs
[ HS Code ]: 2909309014
[ Summary ]:
2909309014 2-nitro-1-(4-nitrophenoxy)-4-(trifluoromethyl)benzene。supervision conditions:s(import or export registration certificate for pesticides)。VAT:17.0%。tax rebate rate:9.0%。MFN tarrif:5.5%。general tariff:30.0%
Articles
Appl. Environ. Microbiol. 73(8) , 2697-707, (2007)
The occurrence and activation of glutathione S-transferase (GST) and the GST activities in biofilms in cold sulfidic spring waters were compared to the occurrence and activation of GST and the GST act...
Triosephosphate isomerases in Italian ryegrass ( Lolium multiflorum ): characterization and susceptibility to herbicides.J. Agric. Food Chem. 57(17) , 7924-30, (2009)
The effect of treatments with four herbicides and a safener on the activity of triosephosphate isomerase (TPI) extracted from shoots of Italian ryegrass was investigated. It was found that atrazine an...
Forced evolution of a herbicide detoxifying glutathione transferase.J. Biol. Chem. 278(26) , 23930-5, (2003)
Plant Tau class glutathione transferases (GSTUs) detoxify diphenylether herbicides such as fluorodifen, determining their selectivity in crops and weeds. Using reconstructive PCR, a series of mutant G...