tBu3PPdG2 catalyst

Names

[ Name ]:
tBu3PPdG2 catalyst

[Synonym ]:
(2'-Amino-2-biphenylyl)(chloro)palladium - tris(2-methyl-2-propanyl)phosphine (1:1)
Palladium, (2'-amino[1,1'-biphenyl]-2-yl)chloro-, compd. with tris(1,1-dimethylethyl)phosphine (1:1)

Chemical & Physical Properties

[ Melting Point ]:
159 °C(dec.)

[ Molecular Formula ]:
C₂₄H₃₇ClNPPd

[ Molecular Weight ]:
512.404

[ Exact Mass ]:
511.138702

Safety Information

[ Hazard Codes ]:
Xn

[ RIDADR ]:
NONH for all modes of transport

Articles

The development of versatile methods for palladium-catalyzed coupling reactions of aryl electrophiles through the use of P(t-Bu)3 and PCy3 as ligands.

Acc. Chem. Res. 41(11) , 1555-64, (2008)

Metal-catalyzed coupling reactions of aryl electrophiles with organometallics and with olefins serve as unusually effective tools for forming new carbon-carbon bonds. By 1998, researchers had develope...

Pd/P(t-Bu)(3): a mild and general catalyst for Stille reactions of aryl chlorides and aryl bromides.

J. Am. Chem. Soc. 124 , 6343, (2003)

Pd/P(t-Bu)(3) serves as an unusually reactive catalyst for Stille reactions of aryl chlorides and bromides, providing solutions to a number of long-standing challenges. An unprecedented array of aryl ...