Di-tert-butylchlorophosphane

[ Density]:
0.951 g/mL at 25 °C(lit.)

[ Boiling Point ]:
191.6±0.0 °C at 760 mmHg

[ Melting Point ]:
2-3°C

[ Molecular Formula ]:
C₈H₁₈ClP

[ Molecular Weight ]:
180.655

[ Flash Point ]:
61.1±0.0 °C

[ Exact Mass ]:
180.083466

[ PSA ]:
13.59000

[ LogP ]:
4.28

[ Vapour Pressure ]:
0.7±0.3 mmHg at 25°C

[ Index of Refraction ]:
n20/D 1.482(lit.)

Click to get detail MSDS

[ Symbol ]:

GHS05

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H314

[ Precautionary Statements ]:
P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
C:Corrosive;

[ Risk Phrases ]:
R34

[ Safety Phrases ]:
S26-S36/37/39-S45-S25

[ RIDADR ]:
UN 3265 8/PG 2

[ WGK Germany ]:
3

[ Packaging Group ]:
II

[ Hazard Class ]:
8

[ HS Code ]:
2903199000

Click to get detail synthetic route

Precursor

DownStream

[ HS Code ]: 2903199000

[ Summary ]:
2903199000 other saturated chlorinated derivatives of acyclic hydrocarbons。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:5.5%。General tariff:30.0%

Synthesis and characterization of R2PN=P(iBuNCH2CH2)3N: a new bulky electron-rich phosphine for efficient Pd-assisted Suzuki-Miyaura cross-coupling reactions.

J. Org. Chem. 72 , 2816, (2007)

Pro-azaphosphatrane 1a [P(iBuNCH2CH2)3N] reacts with iodine under mild conditions to give [IP(iBuNCH2CH2)3N]I in excellent yield, which on subsequent reaction with ammonia followed by deprotonation wi...

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