Tris(pentafluorophenyl)phosphine
Names
[ CAS No. ]:
1259-35-4
[ Name ]:
Tris(pentafluorophenyl)phosphine
[Synonym ]:
Tris(perfluorophenyl)phosphine
Phosphine, tris(pentafluorophenyl)-
MFCD00079654
Phosphine, tris(2,3,4,5,6-pentafluorophenyl)-
EINECS 215-021-2
Tris(pentafluorophenyl)phosphine
tris(2,3,4,5,6-pentafluorophenyl)phosphane
Biological Activity
[Description]:
[Related Catalog]:
[In Vitro]
Chemical & Physical Properties
[ Boiling Point ]:
343.4±42.0 °C at 760 mmHg
[ Melting Point ]:
108-110 °C(lit.)
[ Molecular Formula ]:
C18F15P
[ Molecular Weight ]:
532.15
[ Flash Point ]:
161.5±27.9 °C
[ Exact Mass ]:
531.949829
[ PSA ]:
13.59000
[ LogP ]:
6.24
[ Vapour Pressure ]:
0.0±0.7 mmHg at 25°C
MSDS
Safety Information
[ Symbol ]:
GHS07
[ Signal Word ]:
Warning
[ Hazard Statements ]:
H315-H319-H335
[ Precautionary Statements ]:
P261-P305 + P351 + P338
[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves
[ Hazard Codes ]:
Xi:Irritant;
[ Risk Phrases ]:
R36/37/38
[ Safety Phrases ]:
S26-S36-S37/39
[ RIDADR ]:
NONH for all modes of transport
[ WGK Germany ]:
3
[ HS Code ]:
2903999090
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Customs
[ HS Code ]: 2903999090
[ Summary ]:
2903999090 halogenated derivatives of aromatic hydrocarbons VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%
Articles
J. Am. Chem. Soc. 127(18) , 6573-82, (2005)
Porphyrin-manganese(V)-oxo and porphyrin-manganese(IV)-oxo species were produced in organic solvents by laser flash photolysis (LFP) of the corresponding porphyrin-manganese(III) perchlorate and chlor...
Structure of tris(pentafluorophenyl)phosphine.Acta Crystallogr. C 45 ( Pt 11) , 1743-5, (1989)
C18F15P, Mr = 532.1, monoclinic, P2(1)/c, a = 7.194 (2), b = 17.930 (4), c = 13.834 (2) A, beta = 94.29 (2) degrees, V = 1779 A3, Z = 4, Dm = 2.00, Dx = 1.99 g cm-3, lambda(Mo K alpha) = 0.71073 A, mu...
Probing bare high-valent transition oxo-metal complexes: an electrospray ionization Fourier transform ion cyclotron resonance study of reactive intermediates.Eur. J. Mass Spectrom. (Chichester, Eng.) 16(3) , 407-14, (2010)
Functional models of the Compound I intermediate of monooxygenase heme enzymes, namely [(TPFPP)(*+)Fe(IV)=O](+) and [(TPFPP)Mn(V)=O](+) (TPFPP = meso-tetrakis (pentafluorophenyl)porphyrinato dianion),...